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Substrate-Mediated Interactions and Intermolecular Forces between Molecules Adsorbed on Surfaces

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    Substrate-Mediated Interactions and Intermolecular Forces between Molecules Adsorbed on Surfaces
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    Departments of Chemistry and Physics, The Pennsylvania State University, 152 Davey Laboratory, University Park, Pennsylvania 16802
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    Accounts of Chemical Research

    Cite this: Acc. Chem. Res. 2003, 36, 12, 945–953
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    https://doi.org/10.1021/ar970286l
    Published December 16, 2003
    Copyright © 2003 American Chemical Society
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    Abstract

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    Adsorbate interactions and reactions on metal surfaces have been investigated using scanning tunneling microscopy. The manners in which adsorbates perturb the surface electronic structure in their vicinity are discussed. The effects these perturbations have on other molecules are shown to be important in overlayer growth. Interactions of molecules with surface steps are addressed, and each molecule's electron affinity is shown to dictate its adsorption sites at step edges. Standing waves emanating from steps are demonstrated to effect transient molecular adsorption up to 40 Å away from the step edge. Halobenzene derivatives are used to demonstrate how the surface is important in aligning reactive intermediates.

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    †

     Present address:  Department of Chemistry and Biochemistry, College of Science, University of Notre Dame, Notre Dame, IN 46556.

    ‡

     Present address:  Department of Electrical and Computer Engineering, Rice University, Houston, TX 77005.

    §

     Present address:  Materials Research Institute, The Pennsylvania State University, University Park, PA 16802.

    *

     To whom correspondence should be addressed. E-mail:  [email protected]. Fax:  (814) 863-5516.

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    Cite this: Acc. Chem. Res. 2003, 36, 12, 945–953
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    https://doi.org/10.1021/ar970286l
    Published December 16, 2003
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