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An easily implemented flash photolysis experiment for the physical chemistry laboratory: The isomerization of 4-anilino-4'-nitroazobenzene
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    An easily implemented flash photolysis experiment for the physical chemistry laboratory: The isomerization of 4-anilino-4'-nitroazobenzene
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    Journal of Chemical Education

    Cite this: J. Chem. Educ. 1990, 67, 8, 709
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    https://doi.org/10.1021/ed067p709
    Published August 1, 1990

    Abstract

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    In this experiment, an inexpensive electronic camera flash initiates the reaction, and a visible spectrometer monitors its progress.

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    Cited By

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    This article is cited by 14 publications.

    1. Michael K. Seery, Ariana B. Jones, Will Kew, Thomas Mein. Unfinished Recipes: Structuring Upper-Division Laboratory Work To Scaffold Experimental Design Skills. Journal of Chemical Education 2019, 96 (1) , 53-59. https://doi.org/10.1021/acs.jchemed.8b00511
    2. Molly C. Larsen and Russell J. Perkins . Flash Photolysis Experiment of o-Methyl Red as a Function of pH: A Low-Cost Experiment for the Undergraduate Physical Chemistry Lab. Journal of Chemical Education 2016, 93 (12) , 2096-2100. https://doi.org/10.1021/acs.jchemed.6b00403
    3. Kayrel E. K. Edwards, Ozzy Mermut, William J. Pietro, Christopher J. Barrett. Optical and computational study of the trans ↔ cis reversible isomerization of the commercial bis-azo dye Bismarck Brown Y. Physical Chemistry Chemical Physics 2023, 25 (7) , 5673-5684. https://doi.org/10.1039/D2CP05010B
    4. Swathi Erekath, Kalyani Chordiya, K. V. Vidhya, Mousumi Upadhyay Kahaly, Sreeram K. Kalpathy. Self-aggregation, H-bonding, and photoresponse in film and solution states of azobenzene containing polyurea. Physical Chemistry Chemical Physics 2022, 24 (38) , 23447-23459. https://doi.org/10.1039/D2CP01200F
    5. Maciej Bazarnik, Leszek Jurczyszyn, Ryszard Czajka, Karina Morgenstern. Mechanism of a molecular photo-switch adsorbed on Si(100). Physical Chemistry Chemical Physics 2015, 17 (7) , 5366-5371. https://doi.org/10.1039/C4CP04353G
    6. Zahid Mahimwalla, Kevin Yager, Jun-ichi Mamiya, Atsushi Shishido, Christopher Barrett. Photo-Mechanical Azo Polymers for Light-Powered Actuation and Artificial Muscles. 2012, 107-151. https://doi.org/10.1201/b13892-7
    7. Zahid Mahimwalla, Kevin G. Yager, Jun-ichi Mamiya, Atsushi Shishido, Arri Priimagi, Christopher J. Barrett. Azobenzene photomechanics: prospects and potential applications. Polymer Bulletin 2012, 69 (8) , 967-1006. https://doi.org/10.1007/s00289-012-0792-0
    8. Carolina V. Uliana, Gustavo S. Garbellini, Hideko Yamanaka. Electrochemical reduction of disperse orange 1 textile dye at a boron-doped diamond electrode. Journal of Applied Electrochemistry 2012, 42 (5) , 297-304. https://doi.org/10.1007/s10800-012-0403-7
    9. Gareth O. S. Williams, Jocelyn S. Y. Chen, Tijmen G. Euser, Philip St.J. Russell, Anita C. Jones. Photonic crystal fibre as an optofluidic reactor for the measurement of photochemical kinetics with sub-picomole sensitivity. Lab on a Chip 2012, 12 (18) , 3356. https://doi.org/10.1039/c2lc40062f
    10. Maciej Bazarnik, Jörg Henzl, Ryszard Czajka, Karina Morgenstern. Light driven reactions of single physisorbed azobenzenes. Chemical Communications 2011, 47 (27) , 7764. https://doi.org/10.1039/c1cc11578b
    11. William M. Horspool. The Photochemistry of the Hydrazo, Azo and Azoxy Groups. 2009https://doi.org/10.1002/9780470682531.pat0156
    12. Kevin G. Yager, Christopher J. Barrett. Azobenzene Polymers for Photonic Applications. 2009, 1-46. https://doi.org/10.1002/9780470439098.ch1
    13. Hermann Rau. Photoisomerization of Azobenzenes. 2002, 3-47. https://doi.org/10.1016/B978-012635490-4/50002-0
    14. Kathrin Gille, Helmut Knoll, Konrad Quitzsch. Rate constants of the thermal cis-trans isomerization of azobenzene dyes in solvents, acetone/water mixtures, and in microheterogeneous surfactant solutions. International Journal of Chemical Kinetics 1999, 31 (5) , 337-350. https://doi.org/10.1002/(SICI)1097-4601(1999)31:5<337::AID-KIN3>3.0.CO;2-E

    Journal of Chemical Education

    Cite this: J. Chem. Educ. 1990, 67, 8, 709
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ed067p709
    Published August 1, 1990

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