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Reactivity of Pt0 Complexes toward Gallium(III) Halides: Synthesis of a Platinum Gallane Complex and Oxidative Addition of Gallium Halides to Pt0

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    Reactivity of Pt0 Complexes toward Gallium(III) Halides: Synthesis of a Platinum Gallane Complex and Oxidative Addition of Gallium Halides to Pt0
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    Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
    * To whom correspondence should be addressed. E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2008, 47, 19, 8595–8597
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    https://doi.org/10.1021/ic801293e
    Published September 12, 2008
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    Abstract

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    The reaction of [Pt(PCy3)2] and GaCl3 resulted in quantitative formation of the adduct [(Cy3P)2Pt−GaCl3], the first known platinum gallane complex. Although similar reactivity with GaBr3 and GaI3 was expected, NMR spectroscopic data revealed a different reaction course. Crystal structure determination proved that, in the latter case, the product of the oxidative addition was formed. The resulting platinum gallyl complexes represent the first example of an oxidative addition of gallium(III) halides to low-valent transition metals.

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    Details of the syntheses, spectroscopic characterization, and experimental details on the X-ray diffraction of compounds 4−6 and crystallographic data in CIF format. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: Inorg. Chem. 2008, 47, 19, 8595–8597
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    https://doi.org/10.1021/ic801293e
    Published September 12, 2008
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