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Step-by-Step Route for the Synthesis of Metal−Organic Frameworks
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    Step-by-Step Route for the Synthesis of Metal−Organic Frameworks
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    Ruhr-Universität Bochum, Physikalische Chemie 1, 44780 Bochum, Germany, Universität Tübingen, Angewandte Physik, 72074 Tübingen, Germany, Universität Dortmund, Experimentelle Physik I, 44227 Dortmund, Germany, and Ruhr-Universität Bochum, Organometallics and Materials Chemistry, 44780 Bochum, Germany
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2007, 129, 49, 15118–15119
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    https://doi.org/10.1021/ja076210u
    Published November 17, 2007
    Copyright © 2007 American Chemical Society

    Abstract

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    Using a novel layer-by-layer approach we have deposited metal−organic open frameworks (MOFs) based on benzenetricarboxylic acid ligands and Cu(II)-ions on a COOH-terminated organic surface. The deposited layers were characterized using a number of surface analysis techniques. XRD measurements show that the MOFs deposited using this method have the same bulk structure of HKUST-1.

    Copyright © 2007 American Chemical Society

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     Ruhr-Universität Bochum, Physikalische Chemie.

     Universität Tübingen, Angewandte Physik.

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     Universität Dortmund, Experimentelle Physik I.

     Ruhr-Universität Bochum, Organometallics and Materials Chemistry.

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    IRRAS and NEXAFS spectra recorded for samples prepared after cycles of immersion in Cu(Ac)2 and BTC solutions. IRRAS spectra monitoring the loading of the surface-deposited MOFs with NH3. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Published November 17, 2007
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