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Microencapsulation of a Reactive Liquid-Phase Amine for Self-Healing Epoxy Composites

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Macromolecules 2010, 43, 4, 1855-1859
    Article

    Microencapsulation of a Reactive Liquid-Phase Amine for Self-Healing Epoxy Composites
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    † Department of Materials Science and Engineering
    ‡ Department of Mechanical Science and Engineering
    § Department of Chemistry
    ∥ Department of Aerospace Engineering
    ⊥ Beckman Institute
    University of Illinois at Urbana−Champaign, Urbana, Illinois 61801
    *Corresponding author: e-mail [email protected]
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    Macromolecules

    Cite this: Macromolecules 2010, 43, 4, 1855–1859
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    https://doi.org/10.1021/ma902251n
    Published January 28, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    A method was developed for the preparation of microcapsules containing a reactive amine with potential applications in self-healing polymers. Amine core microcapsules were prepared by interfacial polymerization of an isocyanate and an amine stabilized by an inverse Pickering emulsion. Microcapsules were successfully isolated, dried, and redispersed in epoxy. Visualization of capsules in cured epoxy was carried out by the addition of fluorescent dye to the core material. Mass spectrometry of capsule core material indicated the presence of the desired starting material. Fill content was estimated at 55 wt % by thermogravimetric analysis, and titration of the capsule core material gave an amine equivalent weight of 254 g/mol NH2. Capsules released the core material upon rupture and were able to cure epoxy to form a polymer film.

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    Synthesis solution rheology, emulsion preparation flowchart, summary of experiments performed, and representative DSC thermograms. This material is available free of charge via the Internet at http://pubs.acs.org.

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    This article is cited by 148 publications.

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    7. Marcia W. Patchan, Benedict W. Fuller, Lance M. Baird, Paul K. Gong, Erich C. Walter, Brendan J. Vidmar, Ike Kyei, Zhiyong Xia, and Jason J. Benkoski . Robust Composite-Shell Microcapsules via Pickering Emulsification. ACS Applied Materials & Interfaces 2015, 7 (13) , 7315-7323. https://doi.org/10.1021/acsami.5b00494
    8. Brenda Andrade, Ziyuan Song, Jun Li, Steven C. Zimmerman, Jianjun Cheng, Jeffrey S. Moore, Keith Harris, and Joshua S. Katz . New Frontiers for Encapsulation in the Chemical Industry. ACS Applied Materials & Interfaces 2015, 7 (12) , 6359-6368. https://doi.org/10.1021/acsami.5b00484
    9. Roberto F. A. Teixeira, Otto van den Berg, Le-Thu T. Nguyen, Krisztina Fehér, and Filip E. Du Prez . Microencapsulation of Active Ingredients Using PDMS as Shell Material. Macromolecules 2014, 47 (23) , 8231-8237. https://doi.org/10.1021/ma501897j
    10. Jun Li, Andrew D. Hughes, Tom H. Kalantar, Ian J. Drake, Chris J. Tucker, and Jeffrey S. Moore . Pickering-Emulsion-Templated Encapsulation of a Hydrophilic Amine and Its Enhanced Stability Using Poly(allyl amine). ACS Macro Letters 2014, 3 (10) , 976-980. https://doi.org/10.1021/mz500455j
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    28. A. E. Chalykh, N. Yu. Budylin, A. V. Shapagin. Diffusion in Epoxy Oligomers and Polymers. 2023, 41-105. https://doi.org/10.1007/978-981-19-6038-3_3
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    36. . Basics of Self‐Healing – State of the Art. 2022, 1-63. https://doi.org/10.1002/9781119630005.ch1
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    48. Özge Tezel, Aslı Beyler Çiğil, Memet Vezir Kahraman. Dual microcapsules based epoxy/polyethyleneimine autonomous self‐healing system for photo‐curable coating. Polymers for Advanced Technologies 2021, 32 (2) , 553-563. https://doi.org/10.1002/pat.5109
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    56. Mahboobeh Attaei, Lénia M. Calado, Maryna G. Taryba, Yegor Morozov, R. Abdul Shakoor, Ramazan Kahraman, Ana C. Marques, M. Fátima Montemor. Autonomous self-healing in epoxy coatings provided by high efficiency isophorone diisocyanate (IPDI) microcapsules for protection of carbon steel. Progress in Organic Coatings 2020, 139 , 105445. https://doi.org/10.1016/j.porgcoat.2019.105445
    57. Marya Raji, Mounir El Achaby, Rachid Bouhfid, Abou el kacem Qaiss. Self-healing based on composites and nanocomposites materials: from synthesis to application and modeling. 2020, 41-60. https://doi.org/10.1016/B978-0-08-103013-4.00003-0
    58. Mohammadmahdi Mobaraki, Maryam Ghaffari, Masoud Mozafari. Self-healing polymers for composite structural applications. 2020, 33-51. https://doi.org/10.1016/B978-0-12-817354-1.00003-X
    59. Hakan Burhan, Suna Saygili, Fatih Şen. Enhancements in self-curing composites. 2020, 177-192. https://doi.org/10.1016/B978-0-12-817354-1.00010-7
    60. S. Mojtaba Mirabedini, Farhad Alizadegan. Self-healing polymeric coatings containing microcapsules filled with active materials. 2020, 235-258. https://doi.org/10.1016/B978-0-12-818450-9.00009-X
    61. Maria Kosarli, Dimitrios Bekas, Kyriaki Tsirka, Alkiviadis S. Paipetis. Capsule-based self-healing polymers and composites. 2020, 259-278. https://doi.org/10.1016/B978-0-12-818450-9.00010-6
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    65. Wanessa R. K. Weihermann, Marcia M. Meier, Sergio H. Pezzin. Microencapsulated amino‐functional polydimethylsiloxane as autonomous external self‐healing agent for epoxy systems. Journal of Applied Polymer Science 2019, 136 (23) https://doi.org/10.1002/app.47627
    66. He Zhang, Xin Zhang, Chenlu Bao, Xin Li, Dawei Sun, Fei Duan, Klaus Friedrich, Jinglei Yang. Direct microencapsulation of pure polyamine by integrating microfluidic emulsion and interfacial polymerization for practical self-healing materials. Journal of Materials Chemistry A 2018, 6 (47) , 24092-24099. https://doi.org/10.1039/C8TA08324J
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    68. Cagatay Yilmaz, Mehmet Yildiz, Yusuf Menceloglu. Semi‐intrinsic self‐healing performance of liquid‐cored microcapsules in epoxy matrix. Advances in Polymer Technology 2018, 37 (5) , 1435-1443. https://doi.org/10.1002/adv.21802
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    71. Jamal Seyyed Monfared Zanjani, Burcu Saner Okan, Yusuf Menceloglu, Mehmet Yildiz. Self‐Healing Thermosetting Composites: Concepts, Chemistry, and Future Advances. 2018, 121-150. https://doi.org/10.1002/9783527807130.ch3
    72. Ting Zheng, Srikanth Pilla. Encapsulating Hydrophilic Solution by PU‐PMF Double‐Component Capsule Based on Water‐In‐Oil‐In‐Oil Emulsion Template. Macromolecular Chemistry and Physics 2018, 219 (4) https://doi.org/10.1002/macp.201700418
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    74. Michael W. Keller, Matthew D. Crall. 6.15 Self-Healing Composite Materials. 2018, 431-453. https://doi.org/10.1016/B978-0-12-803581-8.10026-8
    75. Chae Bin Kim, Nam-Ho You, Munju Goh. Hollow polymer microcapsule embedded transparent and heat-insulating film. RSC Advances 2018, 8 (17) , 9480-9486. https://doi.org/10.1039/C8RA00801A
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    78. Manorama Tripathi, Devendra Kumar, Prasun Kumar Roy. Mesoporous silica as amine immobiliser for endowing healing functionality to epoxy resin. Composites Communications 2017, 4 , 20-23. https://doi.org/10.1016/j.coco.2017.03.002
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    81. Parshuram G. Shukla, Siddheshwar B. Jagtap, Satish C. Biradar, Vaibhav P. Charpe, Arun S. Jadhav. Preparation and characterization of microcapsules containing industrially important reactive water-soluble polyamine. Colloid and Polymer Science 2016, 294 (12) , 2039-2050. https://doi.org/10.1007/s00396-016-3966-8
    82. Michiel J.T. Raaijmakers, Nieck E. Benes. Current trends in interfacial polymerization chemistry. Progress in Polymer Science 2016, 63 , 86-142. https://doi.org/10.1016/j.progpolymsci.2016.06.004
    83. Sravendra Rana, Diana Döhler, Ali Shaygan Nia, Mahmood Nasir, Mario Beiner, Wolfgang H. Binder. “Click”‐Triggered Self‐Healing Graphene Nanocomposites. Macromolecular Rapid Communications 2016, 37 (21) , 1715-1722. https://doi.org/10.1002/marc.201600466
    84. Thomas Vidil, François Tournilhac, Simone Musso, Agathe Robisson, Ludwik Leibler. Control of reactions and network structures of epoxy thermosets. Progress in Polymer Science 2016, 62 , 126-179. https://doi.org/10.1016/j.progpolymsci.2016.06.003
    85. Nuttapol Risangud, Thomas R. Congdon, Daniel J. Keddie, Paul Wilson, Kristian Kempe, David M. Haddleton. Polyurea microcapsules from isocyanatoethyl methacrylate copolymers. Journal of Polymer Science Part A: Polymer Chemistry 2016, 54 (17) , 2698-2705. https://doi.org/10.1002/pola.28149
    86. P A Bolimowski, D F Wass, I P Bond. Assessment of microcapsule—catalyst particles healing system in high performance fibre reinforced polymer composite. Smart Materials and Structures 2016, 25 (8) , 084009. https://doi.org/10.1088/0964-1726/25/8/084009
    87. . Self-healing Materials. 2016, 348-402. https://doi.org/10.1039/BK9781849736565-00348
    88. Pengfei Zhang, Guoqiang Li. Advances in healing-on-demand polymers and polymer composites. Progress in Polymer Science 2016, 57 , 32-63. https://doi.org/10.1016/j.progpolymsci.2015.11.005
    89. Wael Ballout, Alain Périchaud, Laura Caserta, Mickael Devassine, Cristina Lavinia Nistor, Rinat Iskakov. Encapsulation methods for photo-polymerisable self-healing formulations. Journal of Microencapsulation 2016, 33 (4) , 331-343. https://doi.org/10.1080/02652048.2016.1194903
    90. Patryk A. Bolimowski, Ian P. Bond, Duncan F. Wass. Robust synthesis of epoxy resin-filled microcapsules for application to self-healing materials. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 2016, 374 (2061) , 20150083. https://doi.org/10.1098/rsta.2015.0083
    91. M. Zhang, S.M. June, T.E. Long, J. Kong. Principles of Step-Growth Polymerization (Polycondensation and Polyaddition). 2016https://doi.org/10.1016/B978-0-12-803581-8.01410-7
    92. M.F. Montemor. Hybrid nanocontainer-based smart self-healing composite coatings for the protection of metallic assets. 2016, 183-209. https://doi.org/10.1016/B978-1-78242-283-9.00007-5
    93. Siddheshwar B. Jagtap, Muthu Subramanian Mohan, Parshuram G. Shukla. Improved performance of microcapsules with polymer nanocomposite wall: Preparation and characterization. Polymer 2016, 83 , 27-33. https://doi.org/10.1016/j.polymer.2015.12.011
    94. Rasoul Esmaeely Neisiany, Saied Nouri Khorasani, Jeremy Kong Yoong Lee, Seeram Ramakrishna. Encapsulation of epoxy and amine curing agent in PAN nanofibers by coaxial electrospinning for self-healing purposes. RSC Advances 2016, 6 (74) , 70056-70063. https://doi.org/10.1039/C6RA06434E
    95. Kunal Wazarkar, Deepak Patil, Ajay Rane, Dinesh Balgude, Mukesh Kathalewar, Anagha Sabnis. Microencapsulation: an emerging technique in the modern coating industry. RSC Advances 2016, 6 (108) , 106964-106979. https://doi.org/10.1039/C6RA13237E
    96. Yongjing Wang, Duc Truong Pham, Chunqian Ji, . Self-healing composites: A review. Cogent Engineering 2015, 2 (1) , 1075686. https://doi.org/10.1080/23311916.2015.1075686
    97. Dong Yu Zhu, Min Zhi Rong, Ming Qiu Zhang. Self-healing polymeric materials based on microencapsulated healing agents: From design to preparation. Progress in Polymer Science 2015, 49-50 , 175-220. https://doi.org/10.1016/j.progpolymsci.2015.07.002
    98. Charles E. Diesendruck, Nancy R. Sottos, Jeffrey S. Moore, Scott R. White. Biomimetische Selbstheilung. Angewandte Chemie 2015, 127 (36) , 10572-10593. https://doi.org/10.1002/ange.201500484
    99. Charles E. Diesendruck, Nancy R. Sottos, Jeffrey S. Moore, Scott R. White. Biomimetic Self‐Healing. Angewandte Chemie International Edition 2015, 54 (36) , 10428-10447. https://doi.org/10.1002/anie.201500484
    100. S.M. Mirabedini, I. Dutil, L. Gauquelin, N. Yan, R.R. Farnood. Preparation of self-healing acrylic latex coatings using novel oil-filled ethyl cellulose microcapsules. Progress in Organic Coatings 2015, 85 , 168-177. https://doi.org/10.1016/j.porgcoat.2015.03.024
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    Cite this: Macromolecules 2010, 43, 4, 1855–1859
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    https://doi.org/10.1021/ma902251n
    Published January 28, 2010
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