Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
Flexible and Transparent Dielectric Film with a High Dielectric Constant Using Chemical Vapor Deposition-Grown Graphene Interlayer

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Nano 2014, 8, 1, 269-274
    Article

    Flexible and Transparent Dielectric Film with a High Dielectric Constant Using Chemical Vapor Deposition-Grown Graphene Interlayer
    Click to copy article linkArticle link copied!

    View Author Information
    † Department of Mechanical Engineering and the Materials Science and Engineering Program, The University of Texas at Austin, Austin, Texas 78712, United States
    ‡ Department of Electrical and Computer Engineering, Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758, United States
    § Department of Organic and Nano System Engineering, Konkuk University, Seoul, 143-701 Korea
    ∥ CNR-IDASC Sensor Lab, Department of Chemistry and Physics, University of Brescia, via Valotti, 9, Brescia 25133, Italy
    School of Mechanical Engineering, Sungkyunkwan University, Suwon, 440-746 Korea
    *Address correspondence to [email protected]
    Other Access OptionsSupporting Information (1)

    ACS Nano

    Cite this: ACS Nano 2014, 8, 1, 269–274
    Click to copy citationCitation copied!
    https://doi.org/10.1021/nn406058g
    Published December 4, 2013
    Copyright © 2013 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    We have devised a dielectric film with a chemical vapor deposited graphene interlayer and studied the effect of the graphene interlayer on the dielectric performance. The highly transparent and flexible film was a polymer/graphene/polymer ‘sandwich-structure’ fabricated by a one-step transfer method that had a dielectric constant of 51, with a dielectric loss of 0.05 at 1 kHz. The graphene interlayer in the film forms a space charge layer, i.e., an accumulation of polarized charge carriers near the graphene, resulting in an induced space charge polarization and enhanced dielectric constant. The characteristic of the space charge layer for the graphene dielectric film, the sheet resistance of the graphene interlayer, was adjusted through thermal annealing that caused partial oxidation. The dielectric film with higher sheet resistance due to the oxidized graphene interlayer had a significantly lower dielectric constant compared to that with the graphene with lower interlayer sheet resistance. Oxidizing the graphene interlayer yields a smaller and thinner space charge density in the dielectric film, ultimately leading to decreased capacitance. Considering the simplicity of the fabrication process and high dielectric performance, as well as the high transparency and flexibility, this film is promising for applications in plastic electronics.

    Copyright © 2013 American Chemical Society

    Subjects

    what are subjects

    Keywords

    what are keywords

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    SEM of the graphene dielectric film; capacitance densities of the dielectric film vs applied frequencies; schematic diagram of the mechanism for enhancing the capacitance; leakage current density vs applied field; intensity of the D- and 2D-bands of the graphene films and position of the 2D-band vs thermal annealing; dielectric constant of the graphene dielectric films vs sheet resistance of the graphene interlayer; tabular comparison of some dielectric properties for various composite materials. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 62 publications.

    1. Huijian Ye, Wenqing Liu, Yafei Chen, Jian Huang, Wei Chen, Zhiyong Chen, Lixin Xu, Jianjun Zhang. Enhanced Polarization in a Graphene/Poly(vinylidene fluoride-co-chlorotrifluoroethylene) Nanocomposite with a Hyperbranched Polyethylene-Grafted Poly(methyl methacrylate) Interface. Industrial & Engineering Chemistry Research 2020, 59 (21) , 9969-9980. https://doi.org/10.1021/acs.iecr.0c00497
    2. Xiuyi Lin, Xi Shen, Xinying Sun, Xu Liu, Ying Wu, Zhenyu Wang, and Jang-Kyo Kim . Graphene Oxide Papers Simultaneously Doped with Mg2+ and Cl– for Exceptional Mechanical, Electrical, and Dielectric Properties. ACS Applied Materials & Interfaces 2016, 8 (3) , 2360-2371. https://doi.org/10.1021/acsami.5b11486
    3. Kaito Nagayama, Taku Goto, Koichi Mayumi, Rina Maeda, Tsuyohito Ito, Yoshiki Shimizu, Kohzo Ito, Yukiya Hakuta, Kazuo Terashima. Composites with aligned and plasma-surface-modified graphene nanoplatelets and high dielectric constants. Materials Letters: X 2024, 22 , 100233. https://doi.org/10.1016/j.mlblux.2024.100233
    4. Zili Tang, Junsong Xia, Hang Yin, Guanghui Fu, Xitong Ai, Hailong Tang, Chaolong Yang, Lunjun Qu, Youbing Li. High-temperature-resistant barium strontium titanate @Ag/poly(arylene ether nitrile) composites with enhanced dielectric performance and high mechanical strength. Advanced Composites and Hybrid Materials 2022, 5 (2) , 823-833. https://doi.org/10.1007/s42114-021-00366-2
    5. Huijian Ye, Huilei Jiang, Zhenggang Luo, Lixin Xu. Elastic interface in few‐layer graphene/poly(vinylidenefluoride‐trifluoroethylene‐chlorofluoroethylene) nanocomposite with improved polarization. Journal of Applied Polymer Science 2022, 139 (17) https://doi.org/10.1002/app.52030
    6. Qiming Tan, Li Yuan, Guozheng Liang, Aijuan Gu. Flexible, transparent, strong and high dielectric constant composite film based on polyionic liquid coated silver nanowire hybrid. Applied Surface Science 2022, 576 , 151827. https://doi.org/10.1016/j.apsusc.2021.151827
    7. D. Bazeia, M. A. Marques, R. Menezes. Maxwell-scalar device based on the electric dipole. Physical Review D 2021, 104 (12) https://doi.org/10.1103/PhysRevD.104.L121703
    8. Xin Zhang, Zihang Shi, Bolun Song, Jianming Feng, Yongan Niu. Reduction, structures, and electrical properties of multi-layer reduced graphene oxide papers by natural sedimentation. Chemical Physics Letters 2021, 785 , 139141. https://doi.org/10.1016/j.cplett.2021.139141
    9. Liangtao Pu, Jing Zhang, Chao Wang, Yifan Pan, Yang Zhao, Yongguang Bu, Quanxing Zhang, Bingcai Pan, Guandao Gao. Membrane cleaning strategy via in situ oscillation driven by piezoelectricity. Journal of Membrane Science 2021, 638 , 119722. https://doi.org/10.1016/j.memsci.2021.119722
    10. Ziyang Zhang, Jigang Du, Jiaxu Li, Xiaodong Huang, Ting Kang, Chi Zhang, Song Wang, Olayemi Oluwatosin Ajao, Wen-Jun Wang, Pingwei Liu. Polymer nanocomposites with aligned two-dimensional materials. Progress in Polymer Science 2021, 114 , 101360. https://doi.org/10.1016/j.progpolymsci.2021.101360
    11. Weiwei Zhao, Mengyue Jiang, Weikang Wang, Shujuan Liu, Wei Huang, Qiang Zhao. Flexible Transparent Supercapacitors: Materials and Devices. Advanced Functional Materials 2021, 31 (11) https://doi.org/10.1002/adfm.202009136
    12. D. Bazeia, M. A. Marques, R. Menezes. Electrically charged localized structures. The European Physical Journal C 2021, 81 (1) https://doi.org/10.1140/epjc/s10052-021-08887-2
    13. Michael Taeyoung Hwang, Mohammad Heiranian, Yerim Kim, Seungyong You, Juyoung Leem, Amir Taqieddin, Vahid Faramarzi, Yuhang Jing, Insu Park, Arend M. van der Zande, Sungwoo Nam, Narayana R. Aluru, Rashid Bashir. Ultrasensitive detection of nucleic acids using deformed graphene channel field effect biosensors. Nature Communications 2020, 11 (1) https://doi.org/10.1038/s41467-020-15330-9
    14. So-Yeon Jun, Donggeun Jung, Jin-Young Kim, SeGi Yu. Dielectric characteristics of graphene-encapsulated barium titanate polymer composites. Materials Chemistry and Physics 2020, 255 , 123533. https://doi.org/10.1016/j.matchemphys.2020.123533
    15. Limei Liu, Junle Qu, Aijuan Gu, Binghao Wang. Percolative polymer composites for dielectric capacitors: a brief history, materials, and multilayer interface design. Journal of Materials Chemistry A 2020, 8 (36) , 18515-18537. https://doi.org/10.1039/D0TA05876A
    16. Jing Fu, Yudong Hou, Xuepeng Liu, Mupeng Zheng, Mankang Zhu. A construction strategy of ferroelectrics by the molten salt method and its application in the energy field. Journal of Materials Chemistry C 2020, 8 (26) , 8704-8731. https://doi.org/10.1039/D0TC01924K
    17. Tony Hiu Tung Fook, Jin Han Jeon, Pooi See Lee. Transparent Flexible Polymer Actuator with Enhanced Output Force Enabled by Conductive Nanowires Interlayer. Advanced Materials Technologies 2020, 5 (1) https://doi.org/10.1002/admt.201900762
    18. Jaehwan Kim, Jung Woong Kim, Hyun Chan Kim, Lindong Zhai, Hyun-U Ko, Ruth M. Muthoka. Review of Soft Actuator Materials. International Journal of Precision Engineering and Manufacturing 2019, 20 (12) , 2221-2241. https://doi.org/10.1007/s12541-019-00255-1
    19. T. Marinho, P. Costa, E. Lizundia, C.M. Costa, S. Corona-Galván, S. Lanceros-Méndez. Ceramic nanoparticles and carbon nanotubes reinforced thermoplastic materials for piezocapacitive sensing applications. Composites Science and Technology 2019, 183 , 107804. https://doi.org/10.1016/j.compscitech.2019.107804
    20. Jianbing Hu. Optimized Dielectric Properties Achieved in Polymer Based Nanocomposites Bearing Wide Bandgap Semiconductors by Tuning Interface Interaction. Journal of Electronic Materials 2019, 48 (9) , 5686-5692. https://doi.org/10.1007/s11664-019-07393-2
    21. Ming Li, Jinzhang Liu, Dezhi Zheng, Mingsheng Zheng, Yi Zhao, Mingjun Hu, G H Yue, Guangcun Shan. Enhanced dielectric permittivity and suppressed electrical conductivity in polyvinylidene fluoride nanocomposites filled with 4,4′-oxydiphenol-functionalized graphene. Nanotechnology 2019, 30 (26) , 265705. https://doi.org/10.1088/1361-6528/ab0a50
    22. Huidong Fan, Shijiao Han, Zhihao Song, Junsheng Yu, Howard E. Katz. Organic field-effect transistor gas sensor based on GO/PMMA hybrid dielectric for the enhancement of sensitivity and selectivity to ammonia. Organic Electronics 2019, 67 , 247-252. https://doi.org/10.1016/j.orgel.2019.01.038
    23. Yajun Wang, Pengfei He, Fuyang Li. Graphene-improved dielectric property of CCTO/PVDF composite film. Ferroelectrics 2019, 540 (1) , 154-161. https://doi.org/10.1080/00150193.2019.1611108
    24. Mohammed H Al-Saleh. Carbon-based polymer nanocomposites as dielectric energy storage materials. Nanotechnology 2019, 30 (6) , 062001. https://doi.org/10.1088/1361-6528/aaf12c
    25. Yuan Ma, Wangshu Tong, Wenjiang Wang, Qi An, Yihe Zhang. Montmorillonite/PVDF-HFP-based energy conversion and storage films with enhanced piezoelectric and dielectric properties. Composites Science and Technology 2018, 168 , 397-403. https://doi.org/10.1016/j.compscitech.2018.10.009
    26. Hakan Usta, Antonio Facchetti. Organic Semiconductors for Transparent Electronics. 2018, 13-49. https://doi.org/10.1002/9783527804894.ch2
    27. Lei Shi, Ruisen Yang, Shiyao Lu, Kun Jia, Chunhui Xiao, Tongqing Lu, Tiejun Wang, Wei Wei, Hui Tan, Shujiang Ding. Dielectric gels with ultra-high dielectric constant, low elastic modulus, and excellent transparency. NPG Asia Materials 2018, 10 (8) , 821-826. https://doi.org/10.1038/s41427-018-0077-7
    28. Jincheng Chen, Bo Fu, Tailin Liu, Zhihong Yan, Kang Li. A simple and fast method for the simultaneous determination of Imperatorin, Isoimperatorin and Umbelliferone at β-CD–GO composite film modified GCE. Sensors and Actuators B: Chemical 2018, 260 , 650-656. https://doi.org/10.1016/j.snb.2017.12.064
    29. Yefeng Feng, Jianxiong Zhang, Jianbing Hu, Shichun Li, Cheng Peng. Significantly Elevated Dielectric and Energy Storage Traits in Boron Nitride Filled Polymer Nano-composites with Topological Structure. Electronic Materials Letters 2018, 14 (2) , 187-197. https://doi.org/10.1007/s13391-018-0032-3
    30. Yefeng Feng, Qin Wu, Jianbing Hu, Zhichao Xu, Cheng Peng, Zexu Xia. Calculating permittivity of semi-conductor fillers in composites based on simplified effective medium approximation models. Materials Research Express 2018, 5 (3) , 035911. https://doi.org/10.1088/2053-1591/aab6f9
    31. Yefeng Feng, Yanmin Dai, Jingjing Sun, Jianbing Hu, Cheng Peng. Simultaneously obtained high permittivity and low loss in 2-2 fluoro-polymer/anti-ferroelectric ceramic composites from interface effect. Materials Research Express 2018, 5 (2) , 026302. https://doi.org/10.1088/2053-1591/aaacdd
    32. Saungeun Park, Hsiao‐Yu Chang, Somayyeh Rahimi, Alvin L. Lee, Li Tao, Deji Akinwande. Transparent Nanoscale Polyimide Gate Dielectric for Highly Flexible Electronics. Advanced Electronic Materials 2018, 4 (2) https://doi.org/10.1002/aelm.201700043
    33. Jiyong Liang, Yizhuo Gu, Zhenchong Zhang, Shaokai Wang, Min Li, Zuoguang Zhang. Densification of chlorine-doped continuous CNT sheet/polyvinylidene fluoride sandwich film and improvement of the mechanical and dielectric properties. Nanotechnology 2018, 29 (3) , 035701. https://doi.org/10.1088/1361-6528/aa9b6c
    34. Yefeng Feng, Jianxiong Zhang, Jianbing Hu, Cheng Peng, Renqi He. Ultra-high polarity ceramics induced extrinsic high permittivity of polymers contributing to high permittivity of 2–2 series composites. Materials Research Express 2018, 5 (1) , 015311. https://doi.org/10.1088/2053-1591/aaa4e6
    35. Leipeng Liu, Penggang Li, Ling Ding, Wangshu Tong, Fengzhu Lv, Yihe Zhang. Utilization of industrial ultra‐fine carbon ash as filler of high‐k composites with high density polyethylene as matrix. Environmental Progress & Sustainable Energy 2017, 36 (6) , 1719-1724. https://doi.org/10.1002/ep.12636
    36. Qingzhong Xue, Qikai Guo, Baoshou Tao, Zhide Han, Jianqiang Zhang, Xinglong Pan. Ultrahigh permittivity of polymer nanocomposites based on surface-modified amorphous carbon/MWCNTs shell/core structured nanohybrids. Composites Part A: Applied Science and Manufacturing 2017, 100 , 324-332. https://doi.org/10.1016/j.compositesa.2017.05.027
    37. Yefeng Feng, Zhichao Xu, Jianbing Hu, Hongpu Huang, Cheng Peng. Significantly reduced dielectric loss and conductivity in polymer-based nano-composites from a suppressed interface Coulomb force. Materials Research Express 2017, 4 (9) , 095001. https://doi.org/10.1088/2053-1591/aa828e
    38. Jeong Eun Baek, Ju Young Kim, Hyeong Min Jin, Bong Hoon Kim, Kyung Eun Lee, Sang Ouk Kim. Single-step self-assembly of multilayer graphene based dielectric nanostructures. FlatChem 2017, 4 , 61-67. https://doi.org/10.1016/j.flatc.2017.06.006
    39. Sangyoon Ji, Jiuk Jang, Eunjin Cho, Si‐Hoon Kim, Eun‐Seok Kang, Jihoon Kim, Han‐Ki Kim, Hoyoul Kong, Sun‐Kyung Kim, Ju‐Young Kim, Jang‐Ung Park. High Dielectric Performances of Flexible and Transparent Cellulose Hybrid Films Controlled by Multidimensional Metal Nanostructures. Advanced Materials 2017, 29 (24) https://doi.org/10.1002/adma.201700538
    40. Hassan Ali, Attia Falak, M A Rafiq, Usman Khan, Shafqat Karim, Adeela Nairan, Tang Jing, Yue Sun, Sibai Sun, Chenjiang Qian, Xiulai Xu. Temperature dependent dielectric and electric modulus properties of ZnS nano particles. Semiconductor Science and Technology 2017, 32 (3) , 035008. https://doi.org/10.1088/1361-6641/aa539c
    41. Sonika Rathi, Gayatri Chauhan, Saral K. Gupta, Ritu Srivastava, Amarjeet Singh. Analysis of Blockade in Charge Transport Across Polymeric Heterojunctions as a Function of Thermal Annealing: A Different Perspective. Journal of Electronic Materials 2017, 46 (2) , 1235-1247. https://doi.org/10.1007/s11664-016-5097-x
    42. Yuanshi Xin, Tongsheng Li, Fanglin Xu, Mingming Wang. Multidimensional structure and enhancement performance of modified graphene/carbon nanotube assemblies in tribological properties of polyimide nanocomposites. RSC Advances 2017, 7 (34) , 20742-20753. https://doi.org/10.1039/C7RA02149F
    43. Xiaobao Zhang, Li Yuan, Qingbao Guan, Guozheng Liang, Aijuan Gu. Greatly improving energy storage density and reducing dielectric loss of carbon nanotube/cyanate ester composites through building a unique tri-layered structure with mica paper. J. Mater. Chem. A 2017, 5 (41) , 21909-21918. https://doi.org/10.1039/C7TA07263E
    44. Li Li, Rui Feng, Yang Zhang, Lijie Dong. Flexible, transparent and high dielectric-constant fluoropolymer-based nanocomposites with a fluoride-constructed interfacial structure. Journal of Materials Chemistry C 2017, 5 (44) , 11403-11410. https://doi.org/10.1039/C7TC03767H
    45. A. B. Phatangare, S. D. Dhole, S. S. Dahiwale, V. L. Mathe, S. V. Bhoraskar, D. J. Late, V. N. Bhoraskar. Surface chemical bonds, surface-enhanced Raman scattering, and dielectric constant of SiO2 nanospheres in-situ decorated with Ag-nanoparticles by electron-irradiation. Journal of Applied Physics 2016, 120 (23) https://doi.org/10.1063/1.4971866
    46. Ga Hun Boo, Jeffery R. Hughey, Kathy Ann Miller, Sung Min Boo. Mitogenomes from type specimens, a genotyping tool for morphologically simple species: ten genomes of agar-producing red algae. Scientific Reports 2016, 6 (1) https://doi.org/10.1038/srep35337
    47. Zhenchong Zhang, Yizhuo Gu, Shaokai Wang, Qingwen Li, Min Li, Zuoguang Zhang. Enhanced dielectric and mechanical properties in chlorine-doped continuous CNT sheet reinforced sandwich polyvinylidene fluoride film. Carbon 2016, 107 , 405-414. https://doi.org/10.1016/j.carbon.2016.05.068
    48. Byoung Gak Kim, Yong Seok Kim, Yun Ho Kim, Hyohye Kim, Ye Ji Hong, Hyun Min Jung, Jong Chan Won. Nano-scale insulation effect of polypyrrole/polyimide core–shell nanoparticles for dielectric composites. Composites Science and Technology 2016, 129 , 153-159. https://doi.org/10.1016/j.compscitech.2016.04.028
    49. Ling Ding, Leipeng Liu, Penggang Li, Fengzhu Lv, Wangshu Tong, Yihe Zhang. Dielectric properties of graphene–iron oxide/polyimide films with oriented graphene. Journal of Applied Polymer Science 2016, 133 (12) https://doi.org/10.1002/app.43041
    50. Yefeng Feng, Honghong Gong, Yunchuan Xie, Xiaoyong Wei, Zhicheng Zhang. Significantly elevated dielectric permittivity of Si-based semiconductor/polymer 2-2 composites induced by high polarity polymers. Journal of Physics D: Applied Physics 2016, 49 (7) , 075503. https://doi.org/10.1088/0022-3727/49/7/075503
    51. Rahim Jan, Amir Habib, Iftikhar Hussain Gul. Stiff, strong, yet tough free-standing dielectric films of graphene nanosheets-polyurethane nanocomposites with very high dielectric constant and loss. Electronic Materials Letters 2016, 12 (1) , 91-99. https://doi.org/10.1007/s13391-015-5235-2
    52. Xinliang Fang, Shanfeng Wang, Yanxiao Li, Xiaoyun Liu, Xinxin Li, Shaoliang Lin, Zhong-Kai Cui, Qixin Zhuang. NH 2 -functionalized carbon-coated Fe 3 O 4 core–shell nanoparticles for in situ preparation of robust polyimide composite films with high dielectric constant, low dielectric loss, and high breakdown strength. RSC Advances 2016, 6 (109) , 107533-107541. https://doi.org/10.1039/C6RA21249B
    53. Bok Ki Min, Seong K. Kim, Seong Jun Kim, Sung Ho Kim, Min-A Kang, Chong-Yun Park, Wooseok Song, Sung Myung, Jongsun Lim, Ki-Seok An. Electrical Double Layer Capacitance in a Graphene-embedded Al2O3 Gate Dielectric. Scientific Reports 2015, 5 (1) https://doi.org/10.1038/srep16001
    54. Jerome A. Cuenca, Evan Thomas, Soumen Mandal, Oliver Williams, Adrian Porch. Investigating the Broadband Microwave Absorption of Nanodiamond Impurities. IEEE Transactions on Microwave Theory and Techniques 2015, 63 (12) , 4110-4118. https://doi.org/10.1109/TMTT.2015.2495156
    55. Tongxing Wang, Li Yuan, Guozheng Liang, Aijuan Gu. Polyaniline coated carbon nanotube/graphene “sandwich” hybrid and its high-k epoxy composites with low dielectric loss and percolation threshold. Applied Surface Science 2015, 359 , 754-765. https://doi.org/10.1016/j.apsusc.2015.10.115
    56. Yong Hun Ko, Yooseok Kim, Daesung Jung, Seung Ho Park, Ji Sun Kim, Jini Shim, Hyeju Yun, Wooseok Song, Chong-Yun Park. Direct Growth of Graphene on Insulating Substrate by Laminated (Au/Ni) Catalyst Layer. Applied Science and Convergence Technology 2015, 24 (4) , 117-124. https://doi.org/10.5757/ASCT.2015.24.4.117
    57. N. A. Nebogatikova, I. V. Antonova, V. Ya. Prinz, I. I. Kurkina, V. I. Vdovin, G. N. Aleksandrov, V. B. Timofeev, S. A. Smagulova, E. R. Zakirov, V. G. Kesler. Fluorinated graphene dielectric films obtained from functionalized graphene suspension: preparation and properties. Physical Chemistry Chemical Physics 2015, 17 (20) , 13257-13266. https://doi.org/10.1039/C4CP04646C
    58. Zhi-cheng Shi, Fan Mao, Jing Wang, Run-hua Fan, Xin Wang. Percolative silver/alumina composites with radio frequency dielectric resonance-induced negative permittivity. RSC Advances 2015, 5 (130) , 107307-107312. https://doi.org/10.1039/C5RA21808J
    59. Binghao Wang, Limei Liu, Guozheng Liang, Li Yuan, Aijuan Gu. Boost up dielectric constant and push down dielectric loss of carbon nanotube/cyanate ester composites via gradient and layered structure design. Journal of Materials Chemistry A 2015, 3 (46) , 23162-23169. https://doi.org/10.1039/C5TA07611K
    60. Jin‐Young Kim, TaeYoung Kim, Ji Won Suk, Harry Chou, Ji‐Hoon Jang, Jong Ho Lee, Iskandar N. Kholmanov, Deji Akinwande, Rodney S. Ruoff. Enhanced Dielectric Performance in Polymer Composite Films with Carbon Nanotube‐Reduced Graphene Oxide Hybrid Filler. Small 2014, 10 (16) , 3405-3411. https://doi.org/10.1002/smll.201400363
    61. Tian Chen, Jinhao Qiu, Kongjun Zhu, Jinhuan Li, Jingwen Wang, Shuqin Li, Xiaoliang Wang. Ultra high permittivity and significantly enhanced electric field induced strain in PEDOT:PSS–RGO@PU intelligent shape-changing electro-active polymers. RSC Adv. 2014, 4 (109) , 64061-64067. https://doi.org/10.1039/C4RA10695D
    62. Yaqin Chen, Baoping Lin, Xueqin Zhang, Junchuan Wang, Changwei Lai, Ying Sun, Yurong Liu, Hong Yang. Enhanced dielectric properties of amino-modified-CNT/polyimide composite films with a sandwich structure. Journal of Materials Chemistry A 2014, 2 (34) , 14118. https://doi.org/10.1039/C4TA01818D
    Download PDF
    Go to ACS Nano
    Get e-Alerts
    Get e-Alerts

    ACS Nano

    Cite this: ACS Nano 2014, 8, 1, 269–274
    Click to copy citationCitation copied!
    https://doi.org/10.1021/nn406058g
    Published December 4, 2013
    Copyright © 2013 American Chemical Society
    Request reuse permissions

    Article Views

    4083

    Altmetric

    -

    Citations

    62
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.