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Single-Site Modifications and Their Effect on the Folding Stability of m-Phenylene Ethynylene Oligomers

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Org. Lett. 2004, 6, 6, 889-892
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    Single-Site Modifications and Their Effect on the Folding Stability of m-Phenylene Ethynylene Oligomers
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    Department of Chemistry and Materials Science & Engineering, 600 South Mathews Avenue, The University of Illinois at Urbana-Champaign, Urbana, Illinois 61801
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    Organic Letters

    Cite this: Org. Lett. 2004, 6, 6, 889–892
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    https://doi.org/10.1021/ol036376+
    Published February 21, 2004
    Copyright © 2004 American Chemical Society
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    Abstract

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    The folded structure of a m-phenylene ethynylene oligomer is tolerant to single-site modifications to both the backbone sequence and end groups. The helical structure is reinforced by multiple noncovalent interactions, allowing the oligomer sequence to be customized without a significant change in stability in most cases. The small changes that are observed are consistent with the expected behavior of π-stacked systems and demonstrate subtle control over folding through single-site modifications.

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    Organic Letters

    Cite this: Org. Lett. 2004, 6, 6, 889–892
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ol036376+
    Published February 21, 2004
    Copyright © 2004 American Chemical Society
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