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Undergraduate Research: Contributions To Organometallic Chemistry

Undergraduate Research: Contributions To Organometallic Chemistry

This Virtual Issue features 24 organometallic chemistry papers from research groups at Primarily Undergraduate Institutions (PUIs) published in four core journals from 2014-2018: Organometallics, Inorganic Chemistry, Organic Letters, and The Journal of Organic Chemistry. The PUI researchers featured here represent a broad spectrum of institutions across the U.S. and Canada, career levels of faculty, and areas of interest. But they all share the common purpose of the pursuit of high-quality research with undergraduates. These reports span the gamut of approaches to organometallic chemistry, ranging from solely computational work to stoichiometric synthetic studies to metal-catalyzed transformations. Topical areas of focus are also incredibly diverse, tapping into coordination chemistry, electrocatalysis/electrochemistry, main-group studies, materials science, and small-molecule activation. It’s clear from these highlighted reports that PUI researchers strive to maintain a presence in emerging frontier areas of organometallic research.

As the guest editors note: "The research featured in this Virtual Issue is a testament to the high-level work that can be performed with undergraduates. …Research for undergraduates is often a transformative experience, providing a natural incubator for the next generation of organometallic chemists."

Please read the full Editorial written by Christopher Bradley and Chip Nataro.


Articles

Article figure
Pd-Catalyzed Conversion of Aryl Iodides to Sulfonyl Fluorides Using SO2 Surrogate DABSO and Selectfluor
  • Ariana L. Tribby
  • , 
  • Ismeraí Rodríguez
  • , 
  • Shamira Shariffudin
  • , and 
  • Nicholas D. Ball*
J. Org. Chem. 2017, 82, 4, 2294-2299
  • Open Access
Publication Date (Web):January 30, 2017
Article figure
Formation, Stability, and Structures of Borenium and Boronium Cations Derived from Pentamethylazaferrocene–Boranes by Hydride or Chloride Abstraction Reactions
  • BriAnne Bentivegna
  • , 
  • Christine I. Mariani
  • , 
  • Jason R. Smith
  • , 
  • Shuhua Ma
  • , 
  • Arnold L. Rheingold
  • , and 
  • Tim J. Brunker*
Organometallics 2014, 33, 11, 2820-2830
    Publication Date (Web):May 23, 2014
    Article figure
    Ester Hydrogenation Catalyzed by CNN-Pincer Complexes of Ruthenium
    • Daniel Kim
    • , 
    • Linh Le
    • , 
    • Myles J. Drance
    • , 
    • Kelsey H. Jensen
    • , 
    • Kristijan Bogdanovski
    • , 
    • Tia N. Cervarich
    • , 
    • Melissa G. Barnard
    • , 
    • Natalie J. Pudalov
    • , 
    • Spring Melody M. Knapp
    • , and 
    • Anthony R. Chianese*
    Organometallics 2016, 35, 7, 982-989
      Publication Date (Web):March 31, 2016
      Article figure
      Syntheses, Characterization, and Reactivity of Diruthenium Hydrido Complexes
      • Heather R. Wiltse
      • , 
      • Alyssa N. Johnson
      • , 
      • Raphael J. Durand
      • , 
      • William Brennessel
      • , and 
      • Robert M. Chin*
      Organometallics 2016, 35, 8, 1079-1085
        Publication Date (Web):April 6, 2016
        Article figure
        Role of Hemilabile Diamine Ligands in the Amine-Directed C–H Borylation of Arenes
        • Lillian V. A. Hale
        • , 
        • Kathryn A. McGarry
        • , 
        • Marissa A. Ringgold
        • , and 
        • Timothy B. Clark*
        Organometallics 2015, 34, 1, 51-55
          Publication Date (Web):December 30, 2014
          Article figure
          Group VI Metal Carbonyl Complexes of Bis((diphenylphosphino)methyl)diphenylborate and an Assessment of Their Utility for Template Ligand Syntheses
          • Paul J. Fischer*
          • , 
          • Laura Avena
          • , 
          • Trent D. Bohrmann
          • , 
          • Michelle C. Neary
          • , 
          • Grace K. Putka
          • , and 
          • Kevin P. Sullivan
          Organometallics 2014, 33, 5, 1300-1309
            Publication Date (Web):February 24, 2014
            Article figure
            Synthesis and Catalytic Activity of (3,4-Diphenylcyclopentadienone)Iron Tricarbonyl Compounds in Transfer Hydrogenations and Dehydrogenations
            • Timothy W. Funk*
            • , 
            • Andrew R. Mahoney
            • , 
            • Rebecca A. Sponenburg
            • , 
            • Kathryn P. Zimmerman
            • , 
            • Daniel K. Kim
            • , and 
            • Emily E. Harrison
            Organometallics 2018, 37, 7, 1133-1140
              Publication Date (Web):March 27, 2018
              Article figure
              Pyridinediimine Iron Complexes with Pendant Redox-Inactive Metals Located in the Secondary Coordination Sphere
              • Mayra Delgado
              • , 
              • Joshua M. Ziegler
              • , 
              • Takele Seda
              • , 
              • Lev N. Zakharov
              • , and 
              • John D. Gilbertson*
              Inorg. Chem. 2016, 55, 2, 555-557
                Publication Date (Web):December 21, 2015
                Article figure
                Electrocatalytic Reduction of CO2 by Group 6 M(CO)6 Species without “Non-Innocent” Ligands
                • Kyle A. Grice*
                •  and 
                • Cesar Saucedo
                Inorg. Chem. 2016, 55, 12, 6240-6246
                  Publication Date (Web):May 26, 2016
                  Article figure
                  Mechanistic Studies on Platinum(II) Catalyzed Hydroarylation of Alkynes
                  • Christine Hahn*
                  • , 
                  • Mayra Miranda
                  • , 
                  • Nagendra P. B. Chittineni
                  • , 
                  • Trent A. Pinion
                  • , and 
                  • Ricardo Perez
                  Organometallics 2014, 33, 12, 3040-3050
                    Publication Date (Web):June 11, 2014
                    Article figure
                    Regiospecific Acylation of Cycloplatinated Complexes: Scope, Limitations, and Mechanistic Implications
                    • Jeffrey Carroll
                    • , 
                    • Hannah G. Woolard
                    • , 
                    • Robert Mroz
                    • , 
                    • Charles A. Nason
                    • , and 
                    • Shouquan Huo*
                    Organometallics 2016, 35, 9, 1313-1322
                      Publication Date (Web):April 29, 2016
                      Article figure
                      Rhodium-Catalyzed Interconversion of Quinolinyl Ketones with Boronic Acids via C–C Bond Activation
                      • Joseph M. Dennis
                      • , 
                      • Chad T. Compagner
                      • , 
                      • Stanna K. Dorn
                      • , and 
                      • Jeffrey B. Johnson*
                      Org. Lett. 2016, 18, 14, 3334-3337
                        Publication Date (Web):July 1, 2016
                        Article figure
                        Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates
                        • Logan W. Sardzinski
                        • , 
                        • William C. Wertjes
                        • , 
                        • Abigail M. Schnaith
                        • , and 
                        • Dipannita Kalyani*
                        Org. Lett. 2015, 17, 5, 1256-1259
                        • Open Access
                        Publication Date (Web):February 20, 2015
                        Article figure
                        Neutral and Cationic Bis-Chelate Monoorganosilicon(IV) Complexes of 1-Hydroxy-2-pyridinone
                        • James G. Koch
                        • , 
                        • William W. Brennessel
                        • , and 
                        • Bradley M. Kraft*
                        Organometallics 2017, 36, 3, 594-604
                          Publication Date (Web):January 13, 2017
                          Article figure
                          Correlations among 31P NMR Coordination Chemical Shifts, Ru–P Bond Distances, and Enthalpies of Reaction in Cp′Ru(PR3)2Cl Complexes (Cp′ = η5-C5H5, η5-C5Me5; PR3 = PMe3, PPhMe2, PPh2Me, PPh3, PEt3, PnBu3)
                          • Alex D. Hunter
                          • , 
                          • Trevor Robert Williams
                          • , 
                          • Brandon M. Zarzyczny
                          • , 
                          • Hans W. Bottesch II
                          • , 
                          • Sara A. Dolan
                          • , 
                          • Kimberly A. McDowell
                          • , 
                          • Dominique Nicole Thomas
                          • , and 
                          • Charles H. Mahler*
                          Organometallics 2016, 35, 16, 2701-2706
                            Publication Date (Web):July 28, 2016
                            Article figure
                            Structural, Computational, and Spectroscopic Investigation of [Pd(κ3-1,1′-bis(di-tert-butylphosphino)ferrocenediyl)X]+ (X = Cl, Br, I) Compounds
                            • Brittany L. Blass
                            • , 
                            • Raúl Hernández Sánchez
                            • , 
                            • Victoria A. Decker
                            • , 
                            • Michael J. Robinson
                            • , 
                            • Nicholas A. Piro
                            • , 
                            • W. Scott Kassel
                            • , 
                            • Paula L. Diaconescu
                            • , and 
                            • Chip Nataro*
                            Organometallics 2016, 35, 4, 462-470
                              Publication Date (Web):February 4, 2016
                              Article figure
                              Base-Free Transfer Hydrogenation of Ketones Using Cp*Ir(pyridinesulfonamide)Cl Precatalysts
                              • Andrew Ruff
                              • , 
                              • Christopher Kirby
                              • , 
                              • Benny C. Chan
                              • , and 
                              • Abby R. O’Connor*
                              Organometallics 2016, 35, 3, 327-335
                                Publication Date (Web):January 14, 2016
                                Article figure
                                Utility of the Nudged Elastic Band Method in Identifying the Minimum Energy Path of an Elementary Organometallic Reaction Step
                                • Kate E. McPherson
                                • , 
                                • Libero J. Bartolotti
                                • , 
                                • Andrew T. Morehead Jr.*
                                • , and 
                                • Andrew L. Sargent*
                                Organometallics 2016, 35, 11, 1861-1865
                                  Publication Date (Web):May 20, 2016
                                  Article figure
                                  One Lump or Two? A Plurality of Pathways in Gold(III)-Catalyzed Cyclization Transforming Propargyl Acetates to a Carene-like Bicyclo[4.1.0]heptane
                                  • Jeremy M. Hines
                                  • , 
                                  • Jesse J. Eason
                                  • , and 
                                  • Matthew R. Siebert*
                                  Organometallics 2017, 36, 4, 920-926
                                    Publication Date (Web):February 6, 2017
                                    Article figure
                                    Gold-Catalyzed Hydroarylation of N-Aryl Alkynamides for the Synthesis of 2-Quinolinones
                                    • Taylor Vacala
                                    • , 
                                    • Lauren P. Bejcek
                                    • , 
                                    • Chloé G. Williams
                                    • , 
                                    • Alexandra C. Williamson
                                    • , and 
                                    • Paul A. Vadola*
                                    J. Org. Chem. 2017, 82, 5, 2558-2569
                                      Publication Date (Web):February 7, 2017
                                      Article figure
                                      Complexes with Tunable Intramolecular Ferrocene to TiIV Electronic Transitions: Models for Solid State FeII to TiIV Charge Transfer
                                      • Michael D. Turlington
                                      • , 
                                      • Jared A. Pienkos
                                      • , 
                                      • Elizabeth S. Carlton
                                      • , 
                                      • Karlee N. Wroblewski
                                      • , 
                                      • Alexis R. Myers
                                      • , 
                                      • Carl O. Trindle
                                      • , 
                                      • Zikri Altun
                                      • , 
                                      • Jeffrey J. Rack
                                      • , and 
                                      • Paul S. Wagenknecht*
                                      Inorg. Chem. 2016, 55, 5, 2200-2211
                                        Publication Date (Web):February 16, 2016
                                        Article figure
                                        Syntheses, Structures, and Mössbauer Effect Spectroscopy of Triple-Decker Complexes Incorporating Nonamethylferrocene
                                        • Andrew J. Schwartz
                                        • , 
                                        • Robert D. Pike
                                        • , 
                                        • Rolfe H. Herber
                                        • , and 
                                        • Eric J. Watson*
                                        Organometallics 2016, 35, 1, 62-69
                                          Publication Date (Web):December 24, 2015
                                          Article figure
                                          Thioboration of α,β-Unsaturated Ketones and Aldehydes toward the Synthesis of β-Sulfido Carbonyl Compounds
                                          • Marc G. Civit
                                          • , 
                                          • Xavier Sanz
                                          • , 
                                          • Christopher M. Vogels
                                          • , 
                                          • Jonathan D. Webb
                                          • , 
                                          • Stephen J. Geier
                                          • , 
                                          • Andreas Decken
                                          • , 
                                          • Carles Bo*
                                          • , 
                                          • Stephen A. Westcott*
                                          • , and 
                                          • Elena Fernández*
                                          J. Org. Chem. 2015, 80, 4, 2148-2154
                                            Publication Date (Web):January 22, 2015
                                            Article figure
                                            Chalcogen Extrusion from Heteroallenes and Carbon Monoxide by a Three-Coordinate Rh(I) Disilylamide
                                            • Matthew T. Whited*
                                            • , 
                                            • Lisa Qiu
                                            • , 
                                            • Alex J. Kosanovich
                                            • , and 
                                            • Daron E. Janzen
                                            Inorg. Chem. 2015, 54, 7, 3670-3679
                                            • Open Access
                                            Publication Date (Web):March 23, 2015

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                                            Previously published research on topics of current scientific interest.

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