Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
Intramolecular C(sp3)–H Bond Activation Reactions of Low-Valent Cobalt Complexes with Coordination Unsaturation

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Organometallics 2012, 31, 20, 7040-7043
    Communication

    Intramolecular C(sp3)–H Bond Activation Reactions of Low-Valent Cobalt Complexes with Coordination Unsaturation
    Click to copy article linkArticle link copied!

    View Author Information
    † State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, People's Republic of China 200032
    ‡ College of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, People's Republic of China 200237
    *Tel: 86-21-54925460. Fax: 86-21-54925460. E-mail: [email protected]
    Other Access OptionsSupporting Information (2)

    Organometallics

    Cite this: Organometallics 2012, 31, 20, 7040–7043
    Click to copy citationCitation copied!
    https://doi.org/10.1021/om300804a
    Published October 9, 2012
    Copyright © 2012 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Intramolecular C(sp3)–H bond activation reactions mediated by low-valent cobalt, both Co(I) and Co(0), have been observed in the reactions of the three-coordinate cobalt complex [Co(IMes)2Cl] (IMes = 1,3-dimesitylimidazol-2-ylidene) with alkylation reagents and sodium amalgam. The reactions with alkylation reagents gave [Co(IMes)(IMes′)(N2)], featuring a metalated IMes′ anion, whereas the one-electron-reduction reaction afforded [Co(IMes′)2]. The Co(II) complex can react with CO, isocyanide, and a diazo compound to furnish interesting cobalt complexes bearing functionalized N-heterocyclic carbene ligands. The establishment of these conversions demonstrates the capability of low-valent cobalt with coordination unsaturation to mediate C(sp3)–H bond activation and functionalization.

    Copyright © 2012 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    Text, a table, figures, and CIF files giving X-ray crystallographic data for complexes 1–7, experimental procedures, and characterization data. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 87 publications.

    1. Sayantani Saha, Jeanette A. Krause, Hairong Guan. C(sp)–H, S–H, and Sn–H Bond Activation with a Cobalt(I) Pincer Complex. Inorganic Chemistry 2024, 63 (29) , 13689-13699. https://doi.org/10.1021/acs.inorgchem.4c01993
    2. Naresh Kumar Meher, Maruti Suryavansi, K. Geetharani. Regioselective Hydroboration of Unsymmetrical Internal Alkynes Catalyzed by a Cobalt Pincer-NHC Complex. Organic Letters 2024, 26 (27) , 5862-5867. https://doi.org/10.1021/acs.orglett.4c02216
    3. Cassandre C. Bories, Alexandre Sodreau, Marion Barbazanges, Marc Petit. Well-Defined Low-Valent Cobalt Complexes in Catalysis: An Overview. Organometallics 2024, 43 (9) , 895-923. https://doi.org/10.1021/acs.organomet.4c00054
    4. Qingshan Wang, Xuebing Leng, Dongyang Wang, Sheng-Di Bai, Liang Deng. Zwitterionic Cobalt(I)–NHC Complexes with Tetraphenylborate Ligation: Synthesis, Characterization, and Reactivity. Organometallics 2024, 43 (6) , 689-694. https://doi.org/10.1021/acs.organomet.4c00011
    5. Li Gu, Addison Fraker, Alex McSkimming. Dynamic N2 Binding at High-Spin Co(I) Supported by N,N,C Heteroscorpionates. Organometallics 2023, 42 (13) , 1621-1628. https://doi.org/10.1021/acs.organomet.3c00183
    6. Naresh Kumar Meher, Piyush Kumar Verma, K. Geetharani. Cobalt-Catalyzed Regioselective 1,2-Hydroboration of N-Heteroarenes. Organic Letters 2023, 25 (1) , 87-92. https://doi.org/10.1021/acs.orglett.2c03891
    7. Qi Chen, Qing Liu, Jie Xiao, Xuebing Leng, Liang Deng. Catalytic Method for the Synthesis of Deuterium-Labeled N-Heterocyclic Carbenes Enabled by a Coordinatively Unsaturated Ruthenium N-Heterocyclic Carbene Catalyst. Journal of the American Chemical Society 2021, 143 (47) , 19956-19965. https://doi.org/10.1021/jacs.1c10071
    8. Idir Benaissa, Katarzyna Gajda, Laure Vendier, Noël Lugan, Anna Kajetanowicz, Karol Grela, Véronique Michelet, Vincent César, Stéphanie Bastin. An Anionic, Chelating C(sp3)/NHC ligand from the Combination of an N-heterobicyclic Carbene and Barbituric Heterocycle. Organometallics 2021, 40 (18) , 3223-3234. https://doi.org/10.1021/acs.organomet.1c00458
    9. Peng Wang, Jun Cheng, Dongyang Wang, Chengbo Yang, Xuebing Leng, Liang Deng. Cobalt(−I)- and Rhodium(−I)-Mediated Dearylation of N-Aryl N-Heterocyclic Carbene Ligands. Organometallics 2020, 39 (15) , 2871-2877. https://doi.org/10.1021/acs.organomet.0c00383
    10. Jingzhen Du, Wenwei Chen, Qi Chen, Xuebing Leng, Yin-Shan Meng, Song Gao, Liang Deng. Reactivity of a Two-Coordinate Cobalt(0) Cyclic (Alkyl)(amino)carbene Complex. Organometallics 2020, 39 (5) , 729-739. https://doi.org/10.1021/acs.organomet.9b00875
    11. Qun Zhao, Guangrong Meng, Steven P. Nolan, Michal Szostak. N-Heterocyclic Carbene Complexes in C–H Activation Reactions. Chemical Reviews 2020, 120 (4) , 1981-2048. https://doi.org/10.1021/acs.chemrev.9b00634
    12. Piyush Kumar Verma, K. Sujit Prasad, Dominic Varghese, K. Geetharani. Cobalt(I)-Catalyzed Borylation of Unactivated Alkyl Bromides and Chlorides. Organic Letters 2020, 22 (4) , 1431-1436. https://doi.org/10.1021/acs.orglett.0c00038
    13. Yang Liu, Jun Cheng, Liang Deng. Three-Coordinate Formal Cobalt(0), Iron(0), and Manganese(0) Complexes with Persistent Carbene and Alkene Ligation. Accounts of Chemical Research 2020, 53 (1) , 244-254. https://doi.org/10.1021/acs.accounts.9b00492
    14. Clifton L. Wagner, Lizhi Tao, James C. Fettinger, R. David Britt, Philip P. Power. Two-Coordinate, Late First-Row Transition Metal Amido Derivatives of the Bulky Ligand -N(SiPri3)Dipp (Dipp = 2,6-diisopropylphenyl): Effects of the Ligand on the Stability of Two-Coordinate Copper(II) Complexes. Inorganic Chemistry 2019, 58 (13) , 8793-8799. https://doi.org/10.1021/acs.inorgchem.9b01159
    15. Chinglin Chan, Alex E. Carpenter, Milan Gembicky, Curtis E. Moore, Arnold L. Rheingold, Joshua S. Figueroa. Associative Ligand Exchange and Substrate Activation Reactions by a Zero-Valent Cobalt Tetraisocyanide Complex. Organometallics 2019, 38 (7) , 1436-1444. https://doi.org/10.1021/acs.organomet.8b00777
    16. Andreas A. Danopoulos, Thomas Simler, Pierre Braunstein. N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt. Chemical Reviews 2019, 119 (6) , 3730-3961. https://doi.org/10.1021/acs.chemrev.8b00505
    17. Parthasarathy Gandeepan, Thomas Müller, Daniel Zell, Gianpiero Cera, Svenja Warratz, Lutz Ackermann. 3d Transition Metals for C–H Activation. Chemical Reviews 2019, 119 (4) , 2192-2452. https://doi.org/10.1021/acs.chemrev.8b00507
    18. Yafei Gao, Lijun Wang, Liang Deng. Distinct Catalytic Performance of Cobalt(I)–N-Heterocyclic Carbene Complexes in Promoting the Reaction of Alkene with Diphenylsilane: Selective 2,1-Hydrosilylation, 1,2-Hydrosilylation, and Hydrogenation of Alkene. ACS Catalysis 2018, 8 (10) , 9637-9646. https://doi.org/10.1021/acscatal.8b02513
    19. Jade Pratt, Aimee M. Bryan, Michelle Faust, Jessica N. Boynton, Petra Vasko, Brian D. Rekken, Akseli Mansikkamäki, James C. Fettinger, Heikki M. Tuononen, Philip P. Power. Effects of Remote Ligand Substituents on the Structures, Spectroscopic, and Magnetic Properties of Two-Coordinate Transition-Metal Thiolate Complexes. Inorganic Chemistry 2018, 57 (11) , 6491-6502. https://doi.org/10.1021/acs.inorgchem.8b00551
    20. Piyush Kumar Verma, Souvik Mandal, K. Geetharani. Efficient Synthesis of Aryl Boronates via Cobalt-Catalyzed Borylation of Aryl Chlorides and Bromides. ACS Catalysis 2018, 8 (5) , 4049-4054. https://doi.org/10.1021/acscatal.8b00536
    21. Yafei Gao, Guangyu Li, and Liang Deng . Bis(dinitrogen)cobalt(−1) Complexes with NHC Ligation: Synthesis, Characterization, and Their Dinitrogen Functionalization Reactions Affording Side-on Bound Diazene Complexes. Journal of the American Chemical Society 2018, 140 (6) , 2239-2250. https://doi.org/10.1021/jacs.7b11660
    22. Daniel Paul, Bernhard Beiring, Markus Plois, Nuria Ortega, Slawomir Kock, Danny Schlüns, Johannes Neugebauer, Robert Wolf, and Frank Glorius . A Cyclometalated Ruthenium-NHC Precatalyst for the Asymmetric Hydrogenation of (Hetero)arenes and Its Activation Pathway. Organometallics 2016, 35 (20) , 3641-3646. https://doi.org/10.1021/acs.organomet.6b00702
    23. Tuo Xi and Zhan Lu . Cobalt-Catalyzed Hydrosilylation/Cyclization of 1,6-Enynes. The Journal of Organic Chemistry 2016, 81 (19) , 8858-8866. https://doi.org/10.1021/acs.joc.6b01555
    24. Sudipta Roy, Kartik Chandra Mondal, and Herbert W. Roesky . Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature. Accounts of Chemical Research 2016, 49 (3) , 357-369. https://doi.org/10.1021/acs.accounts.5b00381
    25. Jian Sun and Liang Deng . Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes. ACS Catalysis 2016, 6 (1) , 290-300. https://doi.org/10.1021/acscatal.5b02308
    26. Zhenwu Ouyang, Jingzhen Du, Lei Wang, Jared L. Kneebone, Michael L. Neidig, and Liang Deng . Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization. Inorganic Chemistry 2015, 54 (17) , 8808-8816. https://doi.org/10.1021/acs.inorgchem.5b01522
    27. Jamie Hicks and Cameron Jones . Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand. Organometallics 2015, 34 (11) , 2118-2121. https://doi.org/10.1021/om501233f
    28. Christopher B. Hansen, Richard F. Jordan, and Gregory L. Hillhouse . Protonolysis and Amide Exchange Reactions of a Three-Coordinate Cobalt Amide Complex Supported by an N-Heterocyclic Carbene Ligand. Inorganic Chemistry 2015, 54 (10) , 4603-4610. https://doi.org/10.1021/ic502670x
    29. Jian Sun, Chong Ou, Chao Wang, Masanobu Uchiyama, and Liang Deng . Silane-Functionalized N-Heterocyclic Carbene–Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co–Si Bond. Organometallics 2015, 34 (8) , 1546-1551. https://doi.org/10.1021/acs.organomet.5b00114
    30. Robert Beck, Ulrich Flörke, and Hans-Friedrich Klein . Cobalt-Promoted Tandem C(sp2)–H Activation and C–C Coupling of Vinyldiphenylphosphine: σ- vs π-Coordination Modes within Cyclometalation. Organometallics 2015, 34 (8) , 1454-1464. https://doi.org/10.1021/om500816t
    31. Zhenbo Mo, Jie Xiao, Yafei Gao, and Liang Deng . Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes. Journal of the American Chemical Society 2014, 136 (50) , 17414-17417. https://doi.org/10.1021/ja510924v
    32. Benjamin M. Day, Kuntal Pal, Thomas Pugh, Jessica Tuck, and Richard A. Layfield . Carbene Rearrangements in Three-Coordinate N-Heterocyclic Carbene Complexes of Cobalt(II) Bis(trimethylsilyl)amide. Inorganic Chemistry 2014, 53 (19) , 10578-10584. https://doi.org/10.1021/ic501677k
    33. Chun-Yi Lin, James C. Fettinger, Fernande Grandjean, Gary J. Long, and Philip P. Power . Synthesis, Structure, and Magnetic and Electrochemical Properties of Quasi-Linear and Linear Iron(I), Cobalt(I), and Nickel(I) Amido Complexes. Inorganic Chemistry 2014, 53 (17) , 9400-9406. https://doi.org/10.1021/ic501534f
    34. Adrian B. Chaplin . Rhodium(I) Complexes of the Conformationally Rigid IBioxMe4 Ligand: Preparation of Mono-, Bis-, and Tris-ligated NHC Complexes. Organometallics 2014, 33 (12) , 3069-3077. https://doi.org/10.1021/om500332n
    35. Adrian B. Chaplin . Rhodium(I) Complexes of the Conformationally Rigid IBioxMe4 Ligand: Isolation of a Stable Low-Coordinate T-Shaped Complex. Organometallics 2014, 33 (3) , 624-626. https://doi.org/10.1021/om401223w
    36. Kartik Chandra Mondal, Prinson P. Samuel, Herbert W. Roesky, Elena Carl, Regine Herbst-Irmer, Dietmar Stalke, Brigitte Schwederski, Wolfgang Kaim, Liviu Ungur, Liviu F. Chibotaru, Markus Hermann, and Gernot Frenking . Stabilization of a Cobalt–Cobalt Bond by Two Cyclic Alkyl Amino Carbenes. Journal of the American Chemical Society 2014, 136 (5) , 1770-1773. https://doi.org/10.1021/ja4123285
    37. Zhenwu Ouyang and Liang Deng . Iron(II) Complexes Featuring Bidentate N-Heterocyclic Carbene–Silyl Ligands: Synthesis and Characterization. Organometallics 2013, 32 (24) , 7268-7271. https://doi.org/10.1021/om4010274
    38. Sarina M. Bellows, Thomas R. Cundari, and Patrick L. Holland . Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)– and Cobalt(II)–Alkyl Complexes. Organometallics 2013, 32 (17) , 4741-4751. https://doi.org/10.1021/om400325x
    39. Jacob A. Przyojski, Hadi D. Arman, and Zachary J. Tonzetich . NHC Complexes of Cobalt(II) Relevant to Catalytic C–C Coupling Reactions. Organometallics 2013, 32 (3) , 723-732. https://doi.org/10.1021/om3010756
    40. Ana Luque-Gómez, Pilar García-Orduña, Fernando J. Lahoz, Manuel Iglesias. Synthesis and catalytic activity of well-defined Co( i ) complexes based on NHC–phosphane pincer ligands. Dalton Transactions 2023, 52 (36) , 12779-12788. https://doi.org/10.1039/D3DT00463E
    41. Yafei Gao, Wei‐Tsung Lee, Veronica Carta, Chun‐Hsing Chen, Joshua Telser, Jeremy M. Smith. Heteroleptic Square Planar Cobalt(I/II) Complexes. European Journal of Inorganic Chemistry 2023, 26 (8) https://doi.org/10.1002/ejic.202200675
    42. Awal Noor. Recent developments in two coordinate transition metal chemistry. Coordination Chemistry Reviews 2023, 476 , 214941. https://doi.org/10.1016/j.ccr.2022.214941
    43. Srinivasa Budagumpi, Rangappa S. Keri, D.H. Nagaraju, Zhoveta Yhobu, V. Monica, B.M. Geetha, Rashmi Dilip Kadu, Nupoor Neole. Progress in the catalytic applications of cobalt N–heterocyclic carbene complexes: Emphasis on their synthesis, structure and mechanism. Molecular Catalysis 2023, 535 , 112850. https://doi.org/10.1016/j.mcat.2022.112850
    44. Gao‐Xiang Wang, Xuechao Yan, Jianhao Yin, Zhu‐Bao Yin, Junnian Wei, Zhenfeng Xi. Cobalt Cyclopentadienyl‐Phosphine Dinitrogen Complexes. Chemistry – A European Journal 2022, 28 (67) https://doi.org/10.1002/chem.202202803
    45. Christian Gunnar Werncke, Andrés G. Gómez. Synthesis, Properties, and Reactivity of Linear Open‐Shell 3d‐Metal(I) Complexes. 2022, 1-30. https://doi.org/10.1002/9781119951438.eibc2796
    46. Qiao Zhang, Simin Wang, Jianjun Yin, Tao Xiong, Qian Zhang. Remote Site‐Selective Asymmetric Protoboration of Unactivated Alkenes Enabled by Bimetallic Relay Catalysis. Angewandte Chemie 2022, 134 (23) https://doi.org/10.1002/ange.202202713
    47. Qiao Zhang, Simin Wang, Jianjun Yin, Tao Xiong, Qian Zhang. Remote Site‐Selective Asymmetric Protoboration of Unactivated Alkenes Enabled by Bimetallic Relay Catalysis. Angewandte Chemie International Edition 2022, 61 (23) https://doi.org/10.1002/anie.202202713
    48. Hongyao Guo, Huan He, Changxi Miao, Weiming Hua, Yinghong Yue, Zi Gao. CO2 assisted ethane dehydrogenation over Co-exchanged ZSM-5 and ZSM-11 zeolites: Effect of Al spatial distribution. Applied Catalysis A: General 2022, 635 , 118569. https://doi.org/10.1016/j.apcata.2022.118569
    49. Liang Deng, Zhenbo Mo. Organometallic Chemistry of NHCs and Analogues. 2022, 339-372. https://doi.org/10.1016/B978-0-12-820206-7.00027-5
    50. Thomas Simler, Andreas A. Danopoulos, Pierre Braunstein. N-Heterocyclic Carbene Complexes of Cobalt. 2022, 632-758. https://doi.org/10.1016/B978-0-12-820206-7.00109-8
    51. Rahul Kumar Singh, Tamanna K. Khan, Shilpi Misra, Amrendra K. Singh. CAACs as efficient ancillary ligands for the synthesis of robust catalysts. Journal of Organometallic Chemistry 2021, 956 , 122133. https://doi.org/10.1016/j.jorganchem.2021.122133
    52. Estefan van Vuuren, Frederick P. Malan, Marilé Landman. Multidentate NHC complexes of group IX metals featuring carbon-based tethers: Synthesis and applications. Coordination Chemistry Reviews 2021, 430 , 213731. https://doi.org/10.1016/j.ccr.2020.213731
    53. Nicolas Mézailles. Reactivity and Structure of Complexes of Small Molecules: Dinitrogen. 2021, 875-958. https://doi.org/10.1016/B978-0-08-102688-5.00083-0
    54. David N. Stephens, Molly O’Hagan, Elliott Hulley, Michael T. Mock. Transition Metal Complexes for Dinitrogen Coordination and Activation. 2021, 363-409. https://doi.org/10.1016/B978-0-08-102688-5.00116-1
    55. Kelly L. Gullett, Joseph W. Nugent, William T. Darrow, Daniel C. Najera, Noah A. Bender, Ericka L. Bruske, Clare A. Leahy, Tabitha J. Miller, Safiyah R. Muhammad, Alison R. Fout. Dihydrogen and Dinitrogen Complexes of Cobalt and Nickel. 2021, 188-228. https://doi.org/10.1016/B978-0-08-102688-5.00094-5
    56. Yafei Gao, Qi Chen, Xuebing Leng, Liang Deng. Cyclometallation reactions of a three-coordinate cobalt( i ) complex bearing a nonsymmetric N-heterocyclic carbene ligand. Dalton Transactions 2019, 48 (26) , 9676-9683. https://doi.org/10.1039/C9DT00731H
    57. Jonghoon Choi, Yunho Lee. A Low‐Spin Three‐Coordinate Cobalt(I) Complex and Its Reactivity toward H 2 and Silane. Angewandte Chemie 2019, 131 (21) , 7012-7016. https://doi.org/10.1002/ange.201901007
    58. Jonghoon Choi, Yunho Lee. A Low‐Spin Three‐Coordinate Cobalt(I) Complex and Its Reactivity toward H 2 and Silane. Angewandte Chemie International Edition 2019, 58 (21) , 6938-6942. https://doi.org/10.1002/anie.201901007
    59. Connie C. Lu, Steven D. Prinslow. Group 9 Transition Metal–Dinitrogen Complexes. 2019, 337-402. https://doi.org/10.1002/9783527344260.ch7
    60. Stefan C. Meier, Albina Holz, Jan Kulenkampff, Alexei Schmidt, Daniel Kratzert, Daniel Himmel, Dominik Schmitz, Ernst‐Wilhelm Scheidt, Wolfgang Scherer, Christine Bülow, Martin Timm, Rebecka Lindblad, Scott T. Akin, Vicente Zamudio‐Bayer, Bernd von Issendorff, Michael A. Duncan, J. Tobias Lau, Ingo Krossing. Access to the Bis‐benzene Cobalt(I) Sandwich Cation and its Derivatives: Synthons for a “Naked” Cobalt(I) Source?. Angewandte Chemie 2018, 130 (30) , 9454-9458. https://doi.org/10.1002/ange.201803108
    61. Stefan C. Meier, Albina Holz, Jan Kulenkampff, Alexei Schmidt, Daniel Kratzert, Daniel Himmel, Dominik Schmitz, Ernst‐Wilhelm Scheidt, Wolfgang Scherer, Christine Bülow, Martin Timm, Rebecka Lindblad, Scott T. Akin, Vicente Zamudio‐Bayer, Bernd von Issendorff, Michael A. Duncan, J. Tobias Lau, Ingo Krossing. Access to the Bis‐benzene Cobalt(I) Sandwich Cation and its Derivatives: Synthons for a “Naked” Cobalt(I) Source?. Angewandte Chemie International Edition 2018, 57 (30) , 9310-9314. https://doi.org/10.1002/anie.201803108
    62. Ryuji Imayoshi, Kazunari Nakajima, Jun Takaya, Nobuharu Iwasawa, Yoshiaki Nishibayashi. Synthesis and Reactivity of Iron– and Cobalt–Dinitrogen Complexes Bearing PSiP‐Type Pincer Ligands toward Nitrogen Fixation. European Journal of Inorganic Chemistry 2017, 2017 (32) , 3769-3778. https://doi.org/10.1002/ejic.201700569
    63. Marcus W. Drover, Cheyenne J. Christopherson, Laurel L. Schafer, Jennifer A. Love. C(sp 3 )–H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)–Phosphoramidate Complex. European Journal of Inorganic Chemistry 2017, 2017 (20) , 2639-2642. https://doi.org/10.1002/ejic.201601518
    64. Jamie Hicks. Preparation of Low Oxidation State Cobalt Complexes Stabilised by a Bulky Amide Ligand. 2017, 131-159. https://doi.org/10.1007/978-981-10-2905-9_5
    65. Anna V. Sberegaeva, David Watts, Andrei N. Vedernikov. Oxidative Functionalization of Late Transition Metal–Carbon Bonds. 2017, 221-297. https://doi.org/10.1016/bs.adomc.2017.03.001
    66. Andreas A. Danopoulos, Pierre Braunstein, Kirill Yu. Monakhov, Jan van Leusen, Paul Kögerler, Martin Clémancey, Jean-Marc Latour, Anass Benayad, Moniek Tromp, Elixabete Rezabal, Gilles Frison. Heteroleptic, two-coordinate [M(NHC){N(SiMe 3 ) 2 }] (M = Co, Fe) complexes: synthesis, reactivity and magnetism rationalized by an unexpected metal oxidation state. Dalton Transactions 2017, 46 (4) , 1163-1171. https://doi.org/10.1039/C6DT03565E
    67. Theresa E. Iannuzzi, Yafei Gao, Tessa M. Baker, Liang Deng, Michael L. Neidig. Magnetic circular dichroism and density functional theory studies of electronic structure and bonding in cobalt( ii )–N-heterocyclic carbene complexes. Dalton Transactions 2017, 46 (39) , 13290-13299. https://doi.org/10.1039/C7DT01748K
    68. Zoë R. Turner. Chemically Non‐Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation. Chemistry – A European Journal 2016, 22 (32) , 11461-11468. https://doi.org/10.1002/chem.201602264
    69. C. Gunnar Werncke, Elizaveta Suturina, Philip C. Bunting, Laure Vendier, Jeffrey R. Long, Mihail Atanasov, Frank Neese, Sylviane Sabo‐Etienne, Sébastien Bontemps. Homoleptic Two‐Coordinate Silylamido Complexes of Chromium(I), Manganese(I), and Cobalt(I). Chemistry – A European Journal 2016, 22 (5) , 1668-1674. https://doi.org/10.1002/chem.201503980
    70. John M. Andjaba, Jesse W. Tye, Pony Yu, Iraklis Pappas, Christopher A. Bradley. Cp*Co(IPr): synthesis and reactivity of an unsaturated Co( i ) complex. Chemical Communications 2016, 52 (12) , 2469-2472. https://doi.org/10.1039/C5CC06756A
    71. Yasuhiro Ohki, Hidetake Seino. N-Heterocyclic carbenes as supporting ligands in transition metal complexes of N 2. Dalton Transactions 2016, 45 (3) , 874-880. https://doi.org/10.1039/C5DT04298D
    72. Abdulrahman D. Ibrahim, Kenan Tokmic, Marshall R. Brennan, Dongyoung Kim, Ellen M. Matson, Mark J. Nilges, Jeffery A. Bertke, Alison R. Fout. Monoanionic bis(carbene) pincer complexes featuring cobalt( I–III ) oxidation states. Dalton Transactions 2016, 45 (24) , 9805-9811. https://doi.org/10.1039/C5DT04723D
    73. Jingzhen Du, Linbo Wang, Meihua Xie, Liang Deng. A Two‐Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity. Angewandte Chemie International Edition 2015, 54 (43) , 12640-12644. https://doi.org/10.1002/anie.201505937
    74. Jingzhen Du, Linbo Wang, Meihua Xie, Liang Deng. A Two‐Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity. Angewandte Chemie 2015, 127 (43) , 12831-12835. https://doi.org/10.1002/ange.201505937
    75. Bo Hu, Andrew “Bean” Getsoian, Neil M. Schweitzer, Ujjal Das, HackSung Kim, Jens Niklas, Oleg Poluektov, Larry A. Curtiss, Peter C. Stair, Jeffrey T. Miller, Adam S. Hock. Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism. Journal of Catalysis 2015, 322 , 24-37. https://doi.org/10.1016/j.jcat.2014.10.018
    76. Yin-Shan Meng, Zhenbo Mo, Bing-Wu Wang, Yi-Quan Zhang, Liang Deng, Song Gao. Observation of the single-ion magnet behavior of d 8 ions on two-coordinate Co( i )–NHC complexes. Chemical Science 2015, 6 (12) , 7156-7162. https://doi.org/10.1039/C5SC02611C
    77. Kartik Chandra Mondal, Sudipta Roy, Susmita De, Pattiyil Parameswaran, Birger Dittrich, Fabian Ehret, Wolfgang Kaim, Herbert W. Roesky. Stabilization of a Two‐Coordinate Mononuclear Cobalt(0) Compound. Chemistry – A European Journal 2014, 20 (37) , 11646-11649. https://doi.org/10.1002/chem.201403525
    78. Gaël Ung, Jonathan Rittle, Michele Soleilhavoup, Guy Bertrand, Jonas C. Peters. Two‐Coordinate Fe 0 and Co 0 Complexes Supported by Cyclic (alkyl)(amino)carbenes. Angewandte Chemie International Edition 2014, 53 (32) , 8427-8431. https://doi.org/10.1002/anie.201404078
    79. Gaël Ung, Jonathan Rittle, Michele Soleilhavoup, Guy Bertrand, Jonas C. Peters. Two‐Coordinate Fe 0 and Co 0 Complexes Supported by Cyclic (alkyl)(amino)carbenes. Angewandte Chemie 2014, 126 (32) , 8567-8571. https://doi.org/10.1002/ange.201404078
    80. Takeshi Yamakawa, Naohiko Yoshikai. Alkene Isomerization–Hydroarylation Tandem Catalysis: Indole C2‐Alkylation with Aryl‐Substituted Alkenes Leading to 1,1‐Diarylalkanes. Chemistry – An Asian Journal 2014, 9 (5) , 1242-1246. https://doi.org/10.1002/asia.201400135
    81. James E. Wheatley, C. André Ohlin, Adrian B. Chaplin. Solvent promoted reversible cyclometalation in a tethered NHC iridium complex. Chem. Commun. 2014, 50 (6) , 685-687. https://doi.org/10.1039/C3CC48015A
    82. Zhenbo Mo, Zhenwu Ouyang, Lei Wang, Kathlyn L. Fillman, Michael L. Neidig, Liang Deng. Two- and three-coordinate formal iron( i ) compounds featuring monodentate aminocarbene ligands. Org. Chem. Front. 2014, 1 (9) , 1040-1044. https://doi.org/10.1039/C4QO00175C
    83. Scott P. Semproni, Crisita Carmen Hojilla Atienza, Paul J. Chirik. Oxidative addition and C–H activation chemistry with a PNP pincer-ligated cobalt complex. Chem. Sci. 2014, 5 (5) , 1956-1960. https://doi.org/10.1039/C4SC00255E
    84. Zhenbo Mo, Yang Liu, Liang Deng. Anchoring of Silyl Donors on a N‐Heterocyclic Carbene through the Cobalt‐Mediated Silylation of Benzylic CH Bonds. Angewandte Chemie International Edition 2013, 52 (41) , 10845-10849. https://doi.org/10.1002/anie.201304596
    85. Zhenbo Mo, Yang Liu, Liang Deng. Anchoring of Silyl Donors on a N‐Heterocyclic Carbene through the Cobalt‐Mediated Silylation of Benzylic CH Bonds. Angewandte Chemie 2013, 125 (41) , 11045-11049. https://doi.org/10.1002/ange.201304596
    86. Katharine A. Smart, Antonia Vanbergen, Jan Lednik, Christina Y. Tang, Hassanatu B. Mansaray, Inke Siewert, Simon Aldridge. Bulky N-heterocyclic carbene and pyridine donor adducts of Co(II) bromide: Influence on reactivity of stoichiometry, sterics and donor capability. Journal of Organometallic Chemistry 2013, 741-742 , 33-39. https://doi.org/10.1016/j.jorganchem.2013.05.020
    87. Andreas A. Danopoulos, Pierre Braunstein. Mono-N-heterocyclic carbene amido and alkyl complexes. Cobalt-mediated C–H activation and C–C coupling reactions involving benzyl ligands on a putative 3-coordinate intermediate. Dalton Transactions 2013, 42 (20) , 7276. https://doi.org/10.1039/c3dt50197c
    Download PDF
    Go to Organometallics
    Get e-Alerts
    Get e-Alerts

    Organometallics

    Cite this: Organometallics 2012, 31, 20, 7040–7043
    Click to copy citationCitation copied!
    https://doi.org/10.1021/om300804a
    Published October 9, 2012
    Copyright © 2012 American Chemical Society
    Request reuse permissions

    Article Views

    3990

    Altmetric

    -

    Citations

    87
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.