Density Functional Theory Modeling of MnO2 Polymorphs as Cathodes for Multivalent Ion BatteriesClick to copy article linkArticle link copied!
- Taylor R. JuranTaylor R. JuranDepartment of Physics, Binghamton University, SUNY, Binghamton 13902, New York, United StatesMore by Taylor R. Juran
- Joshua YoungJoshua YoungDepartment of Physics, Binghamton University, SUNY, Binghamton 13902, New York, United StatesMore by Joshua Young
- Manuel Smeu*Manuel Smeu*E-mail: [email protected]Department of Physics, Binghamton University, SUNY, Binghamton 13902, New York, United StatesMore by Manuel Smeu
Abstract
![Abstract Image](/cms/10.1021/acs.jpcc.8b00918/asset/images/medium/jp-2018-00918p_0006.gif)
Multivalent ion batteries (MVIBs) provide an inexpensive and energy-dense alternative to Li-ion batteries when portability of the battery is not of primary concern. However, it is difficult to find cathode materials that provide optimal battery characteristics such as energy density, adequate charge/discharge rates, and cyclability when paired with a multivalent ion. To address this, we investigate six MnO2 polymorphs as cathodes for MVIBs using density functional theory calculations. We find voltages as high as 3.7, 2.4, 2.7, 1.8, and 1.0 V for Li, Mg, Ca, Al, and Zn, respectively, and calculate the volume change due to intercalation. We then focus specifically on Ca and compute the energy barriers which are associated with the diffusion of the ion throughout the materials. Our findings show that the α-phase displays the most rapid diffusion kinetics for a Ca ion, with a diffusion barrier as low as 190 meV. We then investigate the potential for the five polymorphs exhibiting the highest voltage to intercalate additional atoms and demonstrate that it is energetically favorable for each to accept at least one additional Ca ion; furthermore, two of the phases can accept more than two Ca ions. However, in each case, there is also a corresponding drop in the voltage as further atoms are intercalated. We also utilize a crystal-chemistry approach to detail the structural evolution of each phase by computing the bond valence sum and effective coordination of the Mn4+ ions upon intercalation of increasing numbers of Ca ions. Finally, by computing the electronic density of states, Bader charges, and real space charge density, we describe how the additional electrons from the Ca ions are distributed throughout the unit cell. These insights provide guidance in selecting a MnO2 polymorph with the traits necessary for the realization of MVIBs.
7 × 7 × 7 for α-MnO2, 5 × 5 × 5 for β-MnO2, 7 × 7 × 7 for δ-MnO2, 3 × 3 × 3 for γ-MnO2, 3 × 3 × 3 for λ-MnO2, 7 × 7 × 7 for R-MnO2.
Note: voltages that appear negative actually indicate that the intercalation of the ion is not favorable in that cathode.
Cited By
This article is cited by 74 publications.
- Huiying Zhang, Fanghua Ning, Yiming Guo, Sidra Subhan, Xiaoyu Liu, Siqi Shi, Shigang Lu, Yongyao Xia, Jin Yi. Unraveling the Mechanisms of Aqueous Zinc Ion Batteries via First-Principles Calculations. ACS Energy Letters 2024, Article ASAP.
- Yuchuan Sun, Xiuling Shi, Xiaoying Long, Yibo Weng, Yao Gao, Yan Huang, Kaikai Li. Chemical Strain Analysis of the VO2 Cathode for Zn-Ion Batteries at Different Temperatures. The Journal of Physical Chemistry C 2024, 128
(14)
, 5809-5815. https://doi.org/10.1021/acs.jpcc.4c00233
- Rongrong Mu, Guoquan Suo, Baoguo Zhao, Xiaojiang Hou, Xiaohui Ye, Yanling Yang, Li Zhang. CuS-CTAB Hierarchical Microspheres Anchored on Carbon Fibers as a Flexible Anode for Aqueous Zinc-Ion Batteries. ACS Applied Energy Materials 2024, 7
(4)
, 1590-1597. https://doi.org/10.1021/acsaem.3c02980
- Mohsin Javed, Afzal Shah, Jan Nisar, Suniya Shahzad, Abdul Haleem, Iltaf Shah. Nanostructured Design Cathode Materials for Magnesium-Ion Batteries. ACS Omega 2024, 9
(4)
, 4229-4245. https://doi.org/10.1021/acsomega.3c06576
- Evan Z. Carlson, William C. Chueh, J. Tyler Mefford, Michal Bajdich. Selectivity of Electrochemical Ion Insertion into Manganese Dioxide Polymorphs. ACS Applied Materials & Interfaces 2023, 15
(1)
, 1513-1524. https://doi.org/10.1021/acsami.2c16589
- Xiatong Ye, Hongyi Li, Takuya Hatakeyama, Hiroaki Kobayashi, Toshihiko Mandai, Norihiko L. Okamoto, Tetsu Ichitsubo. Examining Electrolyte Compatibility on Polymorphic MnO2 Cathodes for Room-Temperature Rechargeable Magnesium Batteries. ACS Applied Materials & Interfaces 2022, 14
(51)
, 56685-56696. https://doi.org/10.1021/acsami.2c14193
- Rebecca B. Goncalves, Randall Q. Snurr, Joseph T. Hupp. Computational Investigation of Metal Oxides as Candidate Hydrogen Storage Materials. The Journal of Physical Chemistry C 2022, 126
(44)
, 18661-18669. https://doi.org/10.1021/acs.jpcc.2c04556
- Arturo Torres, José Luis Casals, M. Elena Arroyo-de Dompablo. Enlisting Potential Cathode Materials for Rechargeable Ca Batteries. Chemistry of Materials 2021, 33
(7)
, 2488-2497. https://doi.org/10.1021/acs.chemmater.0c04741
- Haesun Park, Yanjie Cui, Sanghyeon Kim, J. T. Vaughey, Peter Zapol. Ca Cobaltites as Potential Cathode Materials for Rechargeable Ca-Ion Batteries: Theory and Experiment. The Journal of Physical Chemistry C 2020, 124
(11)
, 5902-5909. https://doi.org/10.1021/acs.jpcc.9b11192
- Prashant
Kumar Gupta, Arihant Bhandari, Sulay Saha, Jishnu Bhattacharya, Raj Ganesh S. Pala. Modulating Oxygen Evolution Reactivity in MnO2 through Polymorphic Engineering. The Journal of Physical Chemistry C 2019, 123
(36)
, 22345-22357. https://doi.org/10.1021/acs.jpcc.9b05823
- Joshua Young, Peter M. Kulick, Taylor R. Juran, Manuel Smeu. Comparative Study of Ethylene Carbonate-Based Electrolyte Decomposition at Li, Ca, and Al Anode Interfaces. ACS Applied Energy Materials 2019, 2
(3)
, 1676-1684. https://doi.org/10.1021/acsaem.8b01707
- Aishuak Konarov, Natalia Voronina, Jae Hyeon Jo, Zhumabay Bakenov, Yang-Kook Sun, Seung-Taek Myung. Present and Future Perspective on Electrode Materials for Rechargeable Zinc-Ion Batteries. ACS Energy Letters 2018, 3
(10)
, 2620-2640. https://doi.org/10.1021/acsenergylett.8b01552
- Yu Li, Jie Liu, Yida Deng, Xiaopeng Han, Wenbin Hu, Cheng Zhong. Finite-Element Analysis on Percolation Performance of Foam Zinc. ACS Omega 2018, 3
(9)
, 11018-11025. https://doi.org/10.1021/acsomega.8b01580
- Joshua Young, Manuel Smeu. Ethylene Carbonate-Based Electrolyte Decomposition and Solid–Electrolyte Interphase Formation on Ca Metal Anodes. The Journal of Physical Chemistry Letters 2018, 9
(12)
, 3295-3300. https://doi.org/10.1021/acs.jpclett.8b01261
- Prashant
Kumar Gupta, Arihant Bhandari, Jishnu Bhattacharya, Raj Ganesh S. Pala. Correlating Voltage Profile to Molecular Transformations in Ramsdellite MnO2 and Its Implication for Polymorph Engineering of Lithium Ion Battery Cathodes. The Journal of Physical Chemistry C 2018, 122
(22)
, 11689-11700. https://doi.org/10.1021/acs.jpcc.8b02708
- Ziga Luogu, Qianzhi Gou, Haoran Luo, Zhaoyu Chen, Jiangbin Deng, Kaixin Wang, Yuting He, Yingfang Li, Lei Wang, Ben Zhang, Yujie Zheng, Meng Li. A bio-inspired membrane of interfacial engineering in the cathode in aqueous magnesium-ion batteries. Science China Materials 2024, 67
(8)
, 2558-2566. https://doi.org/10.1007/s40843-024-2962-y
- Tianyun Wang, Xiaowei An, Peifen Wang, Xuli Ma, Yongguo Li, Xiao Du, Xiaogang Hao, Qinglong Luo, Jun Li. Simultaneous selective separation and enrichment of bromine and cesium ions by electrochemically switched amphoteric ion membrane. Desalination 2024, 581 , 117594. https://doi.org/10.1016/j.desal.2024.117594
- Fanjie Ji, Jiamin Yu, Sen Hou, Jinzhao Hu, Shaohui Li. Doping Engineering in Manganese Oxides for Aqueous Zinc-Ion Batteries. Materials 2024, 17
(13)
, 3327. https://doi.org/10.3390/ma17133327
- Qingshuang Zhao, Han Zhang, Xuan Wang, Ting Xu, Meng Zhang, Yaxuan Wang, Lizhong Zhu, Shuhua Tong, Xing Zhou, Jie Li, Weiwei Huan, Zhanhua Huang, Chuanling Si. Highly reversible and rapid charge transfer Zn-MnO2 battery by MnO2 nanosheet arrays anchored nanocellulose-based carbon aerogel. Advanced Composites and Hybrid Materials 2024, 7
(3)
https://doi.org/10.1007/s42114-024-00900-y
- Niklas J. Herrmann, Holger Euchner, Axel Groß, Birger Horstmann. The Cycling Mechanism of Manganese‐Oxide Cathodes in Zinc Batteries: A Theory‐Based Approach. Advanced Energy Materials 2024, 14
(1)
https://doi.org/10.1002/aenm.202302553
- Jimmy-Xuan Shen, Haoming Howard Li, Ann Rutt, Matthew K. Horton, Kristin A. Persson. Topological graph-based analysis of solid-state ion migration. npj Computational Materials 2023, 9
(1)
https://doi.org/10.1038/s41524-023-01051-2
- Nantian Nie, Fuliang Wang, Wenhao Yao. Fabrication of a 3D structure MnO2 electrode with high MnO2 mass loading as the cathode for high-performance aqueous zinc-ion batteries. Electrochimica Acta 2023, 472 , 143423. https://doi.org/10.1016/j.electacta.2023.143423
- Nantian Nie, Fuliang Wang, Wenhao Yao. Fabrication of a Robust and Porous MnO
2
Electrode as the Cathode for High‐Performance Aqueous Zinc‐Ion Batteries. Energy Technology 2023, 11
(12)
https://doi.org/10.1002/ente.202300605
- Da Wang, Zhaomeng Liu, Xuan-Wen Gao, Qinfen Gu, Lukang Zhao, Wen-Bin Luo. Massive anionic fluorine substitution two-dimensional δ-MnO2 nanosheets for high-performance aqueous zinc-ion battery. Journal of Energy Storage 2023, 72 , 108740. https://doi.org/10.1016/j.est.2023.108740
- Hee Jae Kim, Junseo Ahn, Natalia Voronina, Najma Yaqoob, Menno Bokdam, Jiwon Jeong, Jae-Ho Park, Kyung Yoon Chung, Payam Kaghazchi, Seung-Taek Myung. Impact of water on structure stabilization in layered manganese-oxide for high-voltage zinc storage in non-aqueous electrolyte: Experimental and theoretical aspects. Energy Storage Materials 2023, 63 , 103028. https://doi.org/10.1016/j.ensm.2023.103028
- Yuhui Xu, Gaini Zhang, Jingqian Liu, Jianhua Zhang, Xiaoxue Wang, Xiaohua Pu, Jingjing Wang, Cheng Yan, Yanyan Cao, Huijuan Yang, Wenbin Li, Xifei Li. Recent Advances on Challenges and Strategies of Manganese Dioxide Cathodes for Aqueous Zinc‐Ion Batteries. ENERGY & ENVIRONMENTAL MATERIALS 2023, 6
(6)
https://doi.org/10.1002/eem2.12575
- Xin Xiao, Zewen Zhang, Yecun Wu, Jinwei Xu, Xin Gao, Rong Xu, Wenxiao Huang, Yusheng Ye, Solomon T. Oyakhire, Pu Zhang, Baoliang Chen, Emre Cevik, Sarah M Asiri, Ayhan Bozkurt, Khalil Amine, Yi Cui. Ultrahigh‐Loading Manganese‐Based Electrodes for Aqueous Batteries via Polymorph Tuning. Advanced Materials 2023, 35
(33)
https://doi.org/10.1002/adma.202211555
- Feipeng Yang, Xuefei Feng, Zengqing Zhuo, Lauren Vallez, Yi-Sheng Liu, Scott A. McClary, Nathan T. Hahn, Per-Anders Glans, Kevin R. Zavadil, Jinghua Guo. Ca2+ Solvation and Electrochemical Solid/Electrolyte Interphase Formation Toward the Multivalent-Ion Batteries. Arabian Journal for Science and Engineering 2023, 48
(6)
, 7243-7262. https://doi.org/10.1007/s13369-022-07597-5
- Haneen H. Shanaah, Eman F. H. Alzaimoor, Suad Rashdan, Amina A. Abdalhafith, Ayman H. Kamel. Photocatalytic Degradation and Adsorptive Removal of Emerging Organic Pesticides Using Metal Oxide and Their Composites: Recent Trends and Future Perspectives. Sustainability 2023, 15
(9)
, 7336. https://doi.org/10.3390/su15097336
- Guangcai Tan, Shun Wan, Shu-Chuan Mei, Bo Gong, Chen Qian, Jie-Jie Chen. Boosted brackish water desalination and water softening by facilely designed MnO2/hierarchical porous carbon as capacitive deionization electrode. Water Research X 2023, 19 , 100182. https://doi.org/10.1016/j.wroa.2023.100182
- Xilian Xu, Ye Chen, Wanrui Li, Ruilian Yin, Dong Zheng, Xinxin Niu, Xiaojing Dai, Wenhui Shi, Wenxian Liu, Fangfang Wu, Min Wu, Shengli Lu, Xiehong Cao. Achieving Ultralong‐Cycle Zinc‐Ion Battery via Synergistically Electronic and Structural Regulation of a MnO
2
Nanocrystal–Carbon Hybrid Framework. Small 2023, 19
(10)
https://doi.org/10.1002/smll.202207517
- Bidhan Pandit, Sachin R. Rondiya, Shoyebmohamad F. Shaikh, Mohd Ubaidullah, Ricardo Amaral, Nelson Y. Dzade, Emad S. Goda, Abu ul Hassan Sarwar Rana, Harjot Singh Gill, Tokeer Ahmad. Regulated electrochemical performance of manganese oxide cathode for potassium-ion batteries: A combined experimental and first-principles density functional theory (DFT) investigation. Journal of Colloid and Interface Science 2023, 633 , 886-896. https://doi.org/10.1016/j.jcis.2022.11.070
- David A. Santos, Shahed Rezaei, Delin Zhang, Yuting Luo, Binbin Lin, Ananya R. Balakrishna, Bai-Xiang Xu, Sarbajit Banerjee. Chemistry–mechanics–geometry coupling in positive electrode materials: a scale-bridging perspective for mitigating degradation in lithium-ion batteries through materials design. Chemical Science 2023, 14
(3)
, 458-484. https://doi.org/10.1039/D2SC04157J
- Mengcheng Wu, Wanying Zheng, Xi Hu, Feiyang Zhan, Qingqing He, Huayu Wang, Qichun Zhang, Lingyun Chen. Exploring 2D Energy Storage Materials: Advances in Structure, Synthesis, Optimization Strategies, and Applications for Monovalent and Multivalent Metal‐Ion Hybrid Capacitors. Small 2022, 18
(50)
https://doi.org/10.1002/smll.202205101
- Kethaki Wickramaarachchi, Manickam Minakshi. Status on electrodeposited manganese dioxide and biowaste carbon for hybrid capacitors: The case of high-quality oxide composites, mechanisms, and prospects. Journal of Energy Storage 2022, 56 , 106099. https://doi.org/10.1016/j.est.2022.106099
- Nicolas P. L. Magnard, Andy S. Anker, Olivia Aalling-Frederiksen, Andrea Kirsch, Kirsten M. Ø. Jensen. Characterisation of intergrowth in metal oxide materials using structure-mining: the case of γ-MnO
2. Dalton Transactions 2022, 51
(45)
, 17150-17161. https://doi.org/10.1039/D2DT02153F
- Kaveen Sandagiripathira, Mohammad Ali Moghaddasi, Robert Shepard, Manuel Smeu. Investigating the role of structural water on the electrochemical properties of α-V
2
O
5
through density functional theory. Physical Chemistry Chemical Physics 2022, 24
(39)
, 24271-24280. https://doi.org/10.1039/D1CP05291H
- Robert Shepard, Scott Brennan, Taylor R Juran, Joshua Young, Manuel Smeu. Ab initio
determination of a simultaneous dual-ion charging mechanism for Ni
0.25
Mn
0.75
O
2
through redox reactions of Ni
2+
/Ni
4+
and O
2−
/O
−. Journal of Materials Chemistry A 2022, 10
(36)
, 18916-18927. https://doi.org/10.1039/D2TA03938A
- James Kumankuma-Sarpong, Wei Guo, Yongzhu Fu. Advances of Metal Oxide Composite Cathodes for Aqueous Zinc‐Ion Batteries. Advanced Energy and Sustainability Research 2022, 3
(6)
https://doi.org/10.1002/aesr.202100220
- Qianzhi Gou, Haoran Luo, Yujie Zheng, Qi Zhang, Chen Li, Jiacheng Wang, Omololu Odunmbaku, Jing Zheng, Junmin Xue, Kuan Sun, Meng Li. Construction of Bio‐inspired Film with Engineered Hydrophobicity to Boost Interfacial Reaction Kinetics of Aqueous Zinc–Ion Batteries. Small 2022, 18
(24)
https://doi.org/10.1002/smll.202201732
- Yixuan Guo, Yixiang Zhang, Hongbin Lu. Manganese‐based materials as cathode for rechargeable aqueous zinc‐ion batteries. Battery Energy 2022, 1
(2)
https://doi.org/10.1002/bte2.20210014
- Gaoxue Jiang, Yurong Ren, Xiaobing Huang, Jianmin Ma. Zn‐Ion Battery. 2022, 201-227. https://doi.org/10.1002/9783527830053.ch6
- Hyeri Bu, Hyungjin Lee, Dedy Setiawan, Seung-Tae Hong. Intercalation-type positive electrode materials for nonaqueous calcium-ion batteries. Chemical Physics Reviews 2022, 3
(1)
https://doi.org/10.1063/5.0073087
- Diana Liepinya, Robert Shepard, Manuel Smeu. 2D Ni0.25Mn0.75O2: A high-performance cathode for multivalent ion batteries. Computational Materials Science 2022, 202 , 110948. https://doi.org/10.1016/j.commatsci.2021.110948
- Tao Zhou, Limin Zhu, Lingling Xie, Qing Han, Xinli Yang, Lei Chen, Gongke Wang, Xiaoyu Cao. Cathode materials for aqueous zinc-ion batteries: A mini review. Journal of Colloid and Interface Science 2022, 605 , 828-850. https://doi.org/10.1016/j.jcis.2021.07.138
- Susu Chen, Dong Zhao, Long Chen, Guangrong Liu, Yan Ding, Yuliang Cao, Zhongxue Chen. Emerging Intercalation Cathode Materials for Multivalent Metal‐Ion Batteries: Status and Challenges. Small Structures 2021, 2
(11)
https://doi.org/10.1002/sstr.202100082
- Dipayan Pal, Sudip Chakraborty, Sudeshna Chattopadhyay. Recent Progress in Al‐, K‐, and Zn‐Ion Batteries: Experimental and Theoretical Viewpoints. Energy Technology 2021, 9
(9)
https://doi.org/10.1002/ente.202100382
- Xingyuan Gao, Jinmiao Zhang, Wei Yin, Xihong Lu. Recent progress and challenges of co‐based compound for aqueous Zn battery. Nano Select 2021, 2
(9)
, 1642-1660. https://doi.org/10.1002/nano.202100035
- Wending Pan, Jianjun Mao, Yifei Wang, Xiaolong Zhao, Kee Wah Leong, Shijing Luo, Yue Chen, Dennis Y. C. Leung. High‐Performance MnO
2
/Al Battery with In Situ Electrochemically Reformed Al
x
MnO
2
Nanosphere Cathode. Small Methods 2021, 5
(9)
https://doi.org/10.1002/smtd.202100491
- Joshua Young, Manuel Smeu. Preventing Electrolyte Decomposition on a Ca Metal Electrode Interface Using an Artificial Solid‐Electrolyte Interphase. Advanced Theory and Simulations 2021, 4
(8)
https://doi.org/10.1002/adts.202100018
- Fabio Maroni, Saustin Dongmo, Cornelius Gauckler, Mario Marinaro, Margret Wohlfahrt‐Mehrens. Through the Maze of Multivalent‐Ion Batteries: A Critical Review on the Status of the Research on Cathode Materials for Mg
2+
and Ca
2+
Ions Insertion. Batteries & Supercaps 2021, 4
(8)
, 1221-1251. https://doi.org/10.1002/batt.202000330
- Biswajit Ball, Pranab Sarkar. Tuning the structural skeleton of a phenanthroline-based covalent organic framework for better electrochemical performance as a cathode material for Zn-ion batteries: a theoretical exploration. Physical Chemistry Chemical Physics 2021, 23
(22)
, 12644-12653. https://doi.org/10.1039/D1CP01209F
- Chunhong Chen, Fangyi Shi, Zheng-Long Xu. Advanced electrode materials for nonaqueous calcium rechargeable batteries. Journal of Materials Chemistry A 2021, 9
(20)
, 11908-11930. https://doi.org/10.1039/D1TA00757B
- Yaning Gao, Haoyi Yang, Ying Bai, Chuan Wu. Mn-based oxides for aqueous rechargeable metal ion batteries. Journal of Materials Chemistry A 2021, 9
(19)
, 11472-11500. https://doi.org/10.1039/D1TA01951A
- Hyunwoo Kim, Woosung Choi, Jaesang Yoon, Eunkang Lee, Won‐Sub Yoon. Polymorphic Effects on Electrochemical Performance of Conversion‐Based MnO
2
Anode Materials for Next‐Generation Li Batteries. Small 2021, 17
(14)
https://doi.org/10.1002/smll.202006433
- Bo Zhou, Zhaoyu Zhou, Bo Li, Zilin Qu, Qi Song, Chunmei Zhang, Zhenyi Jiang, Yi Ding. Theoretical evaluation of multivalent cation diffusion in the 1T-δ-MnO
2
electrode via potential energy surface. Journal of Physics D: Applied Physics 2021, 54
(11)
, 115303. https://doi.org/10.1088/1361-6463/abcf75
- Yuan Tian, Yongling An, Chuanliang Wei, Baojuan Xi, Shenglin Xiong, Jinkui Feng, Yitai Qian. Recent Advances and Perspectives of Zn‐Metal Free “Rocking‐Chair”‐Type Zn‐Ion Batteries. Advanced Energy Materials 2021, 11
(5)
https://doi.org/10.1002/aenm.202002529
- Bifa Ji, Haiyan He, Wenjiao Yao, Yongbing Tang. Recent Advances and Perspectives on Calcium‐Ion Storage: Key Materials and Devices. Advanced Materials 2021, 33
(2)
https://doi.org/10.1002/adma.202005501
- Mei Er Pam, Dong Yan, Juezhi Yu, Daliang Fang, Lu Guo, Xue Liang Li, Tian Chen Li, Xunyu Lu, Lay Kee Ang, Rose Amal, Zhaojun Han, Hui Ying Yang. Microstructural Engineering of Cathode Materials for Advanced Zinc‐Ion Aqueous Batteries. Advanced Science 2021, 8
(1)
https://doi.org/10.1002/advs.202002722
- Ryan D. Corpuz, Lyn Marie De Juan-Corpuz, Soorathep Kheawhom. Manganese Dioxide (MnO2): A High-Performance Energy Material for Electrochemical Energy Storage Applications. 2021, 91-119. https://doi.org/10.1007/978-3-030-53065-5_3
- Jing Huang, Ruimei Fang, Yanjuan Sun, Jieyuan Li, Fan Dong. Efficient α-MnO2 with (2 1 0) facet exposed for catalytic oxidation of toluene at low temperature: A combined in-situ DRIFTS and theoretical investigation. Chemosphere 2021, 263 , 128103. https://doi.org/10.1016/j.chemosphere.2020.128103
- Joshua Fu, Xuan Luo. A first-principles investigation of α, β, and γ-MnO
2
as potential cathode materials in Al-ion batteries. RSC Advances 2020, 10
(65)
, 39895-39900. https://doi.org/10.1039/D0RA08401H
- Simon Clark, Niklas Borchers, Zenonas Jusys, R. Jürgen Behm, Birger Horstmann. Aqueous Zinc Batteries. 2020, 1-54. https://doi.org/10.1002/9783527610426.bard110022
- Yinlei Zhao, Yunhai Zhu, Xinbo Zhang. Challenges and perspectives for manganese‐based oxides for advanced aqueous zinc‐ion batteries. InfoMat 2020, 2
(2)
, 237-260. https://doi.org/10.1002/inf2.12042
- Kingo Ariyoshi, Shumpei Masuda. Mechanism of Mg extraction from MgMn
2
O
4
during acid digestion. Physical Chemistry Chemical Physics 2020, 22
(8)
, 4677-4684. https://doi.org/10.1039/C9CP05829J
- Yun‐Hai Zhu, Xiao‐Yang Yang, Tong Liu, Xin‐Bo Zhang. Flexible 1D Batteries: Recent Progress and Prospects. Advanced Materials 2020, 32
(5)
https://doi.org/10.1002/adma.201901961
- Chuyu Zhu, Guozhao Fang, Shuquan Liang, Zixian Chen, Ziqing Wang, Jingyuan Ma, Han Wang, Boya Tang, Xusheng Zheng, Jiang Zhou. Electrochemically induced cationic defect in MnO intercalation cathode for aqueous zinc-ion battery. Energy Storage Materials 2020, 24 , 394-401. https://doi.org/10.1016/j.ensm.2019.07.030
- Muhammad Hilmy Alfaruqi, Saiful Islam, Jun Lee, Jeonggeun Jo, Vinod Mathew, Jaekook Kim. First principles calculations study of α-MnO
2
as a potential cathode for Al-ion battery application. Journal of Materials Chemistry A 2019, 7
(47)
, 26966-26974. https://doi.org/10.1039/C9TA09321D
- Boya Tang, Lutong Shan, Shuquan Liang, Jiang Zhou. Issues and opportunities facing aqueous zinc-ion batteries. Energy & Environmental Science 2019, 12
(11)
, 3288-3304. https://doi.org/10.1039/C9EE02526J
- Taylor R. Juran, Manuel Smeu. TiSe2 cathode for beyond Li-ion batteries. Journal of Power Sources 2019, 436 , 226813. https://doi.org/10.1016/j.jpowsour.2019.226813
- Huixin Zhang, Ayman Alameen, Xiaowei An, Qianyao Shen, Lutong Chang, Shengqi Ding, Xiao Du, Xuli Ma, Xiaogang Hao, Changjun Peng. Theoretical and experimental investigations of BiOCl for electrochemical adsorption of cesium ions. Physical Chemistry Chemical Physics 2019, 21
(37)
, 20901-20908. https://doi.org/10.1039/C9CP03684A
- Dinesh Selvakumaran, Anqiang Pan, Shuquan Liang, Guozhong Cao. A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries. Journal of Materials Chemistry A 2019, 7
(31)
, 18209-18236. https://doi.org/10.1039/C9TA05053A
- Huixin Zhang, Xiao Du, Shengqi Ding, Qiang Wang, Lutong Chang, Xuli Ma, Xiaogang Hao, Changjun Pen. DFT calculations of the synergistic effect of λ-MnO
2
/graphene composites for electrochemical adsorption of lithium ions. Physical Chemistry Chemical Physics 2019, 21
(15)
, 8133-8140. https://doi.org/10.1039/C9CP00714H
- Vivek Verma, Sonal Kumar, William Manalastas, Rohit Satish, Madhavi Srinivasan. Progress in Rechargeable Aqueous Zinc‐ and Aluminum‐Ion Battery Electrodes: Challenges and Outlook. Advanced Sustainable Systems 2019, 3
(1)
https://doi.org/10.1002/adsu.201800111
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.