Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
Cobalt Hydrogen-Bonded Organic Framework as a Visible Light-Driven Photocatalyst for CO2 Cycloaddition Reaction

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2023, 62, 38, 15550-15564
    Article

    Cobalt Hydrogen-Bonded Organic Framework as a Visible Light-Driven Photocatalyst for CO2 Cycloaddition Reaction
    Click to copy article linkArticle link copied!

    • Lamia A. Siddig
      Lamia A. Siddig
      Department of Chemistry, UAE University, P.O. Box 15551, Al-Ain 15551, UAE
      More by Lamia A. Siddig
    • Reem H. Alzard
      Reem H. Alzard
      Department of Chemistry, UAE University, P.O. Box 15551, Al-Ain 15551, UAE
      More by Reem H. Alzard
    • Abdalla S. Abdelhamid
      Abdalla S. Abdelhamid
      Department of Chemistry, UAE University, P.O. Box 15551, Al-Ain 15551, UAE
      Department of Chemical Engineering, UAE University, P.O. Box 15551, Al-Ain 15551, UAE
      More by Abdalla S. Abdelhamid
    • Tholkappiyan Ramachandran
      Tholkappiyan Ramachandran
      Department of Physics, UAE University, P.O. Box 15551, Al-Ain 15551,UAE
      More by Tholkappiyan Ramachandran
    • Ha L. Nguyen
      Ha L. Nguyen
      Berkeley Global Science Institute, University of California Berkeley, Berkeley,California 94720, United States
      More by Ha L. Nguyen
      Orcidhttps://orcid.org/0000-0002-4977-925X
    • Alejandro Perez Paz*
      Alejandro Perez Paz
      Department of Chemistry, UAE University, P.O. Box 15551, Al-Ain 15551, UAE
      *Email: [email protected]
      More by Alejandro Perez Paz
    • Ahmed Alzamly*
      Ahmed Alzamly
      Department of Chemistry, UAE University, P.O. Box 15551, Al-Ain 15551, UAE
      *Email: [email protected]
      More by Ahmed Alzamly
      Orcidhttps://orcid.org/0000-0002-7586-9785
    Other Access OptionsSupporting Information (1)

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2023, 62, 38, 15550–15564
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.3c02051
    Published September 12, 2023
    Copyright © 2023 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    A novel cobalt hydrogen-bonded organic framework (Co-HOF, C24H14CoN4O8) was synthesized from a mixed linker, that is, 2,5-pyridinedicarboxylic acid (PDC) and 2,2′-bipyridyl (BPY) linkers and cobalt ion through a simple, one-pot, low-cost, and scalable solvothermal method. The Co-HOF was fully characterized using several analytical and spectroscopic techniques including single-crystal X-ray diffraction, diffuse reflectance spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray, and X-ray photoelectron spectroscopy. The Co-HOF exhibits high thermal and chemical stabilities compared to previously reported HOF materials. Moreover, Co-HOF shows excellent photocatalytic activity under visible light irradiation due to its narrow band gap of 2.05 eV. The cycloaddition reaction of CO2 to variable epoxides was investigated to evaluate the photocatalytic performance of Co-HOF under visible light radiation and was found to produce the corresponding cyclic carbonates in yields up to 99.9%.

    Copyright © 2023 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c02051.

    • DFT-relaxed structures of the crystal and gas-phase monomer and animation of the binding of ethylene oxide to the cobalt complex of formula CoO8N4C24H15 with the two relevant interatom distances indicated in Å (PDF)

    Accession Codes

    CCDC 2269819 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 5 publications.

    1. Jing Dong, Long Huang, Le Shi, Jiong Yang, Yi Wan, Dong Shao. Metalo Hydrogen-Bonded Organic Frameworks Constructed by Coordinated Chains for Magnetic and Proton-Conductive Bifunctionality. Inorganic Chemistry 2024, Article ASAP.
    2. Guang-Lu Li, Kai-Kai Niu, Xuan-Zong Yang, Hui Liu, Shengsheng Yu, Ling-Bao Xing. A Hydrogen-Bonded Organic Framework Based on Triphenylamine for Photocatalytic Silane Hydroxylation. Inorganic Chemistry 2024, 63 (35) , 16533-16540. https://doi.org/10.1021/acs.inorgchem.4c02886
    3. Lingjing Jiang, Dengqi Wu, Zishan Huang, Fengfeng Chen, Kai Chen, Aziz Bakhtiyarovich Ibragimov, Junkuo Gao. In Situ Pyrolysis of ZIF-67 to Construct Co2N0.67@ZIF-67 for Photocatalytic CO2 Cycloaddition Reaction. Inorganic Chemistry 2024, 63 (31) , 14761-14769. https://doi.org/10.1021/acs.inorgchem.4c02504
    4. Bin Jiang, Congcong Zhang, Na Yang, Qi Zhou, Longfei Zhang, Jingshuai Li, Wei Yang, Xiaodong Yang, Luhong Zhang. 2D/2D ZIF-L-Derived Znδ+ (0 ≤ δ ≤ 2) and N Codoped Carbon Skeleton@ZnIn2S4 S-Scheme Heterojunction for Solar-Driven CO2 Cycloaddition. ACS Sustainable Chemistry & Engineering 2024, 12 (17) , 6584-6595. https://doi.org/10.1021/acssuschemeng.3c08407
    5. Kelong Liu, Longchao Du, Tingting Wang. Coordination Synergy between Iridium Photosensitizers and Metal Nanoclusters Leading to Enhanced CO2 Cycloaddition under Mild Conditions. Inorganic Chemistry 2024, 63 (10) , 4614-4627. https://doi.org/10.1021/acs.inorgchem.3c04181
    Download PDF
    Go to Inorganic Chemistry
    Get e-Alerts
    Get e-Alerts

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2023, 62, 38, 15550–15564
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.3c02051
    Published September 12, 2023
    Copyright © 2023 American Chemical Society
    Request reuse permissions

    Article Views

    1348

    Altmetric

    -

    Citations

    5
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.