Conductive Mesoporous Niobium Nitride Microspheres/Nitrogen-Doped Graphene Hybrid with Efficient Polysulfide Anchoring and Catalytic Conversion for High-Performance Lithium–Sulfur BatteriesClick to copy article linkArticle link copied!
- Xingxing LiXingxing LiThe State Key Laboratory of Refractories and Metallurgy and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaMore by Xingxing Li
- Biao GaoBiao GaoThe State Key Laboratory of Refractories and Metallurgy and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaDepartment of Physics and Department of Materials Science and Engineering, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong 999077, ChinaMore by Biao Gao
- Xian HuangXian HuangThe State Key Laboratory of Refractories and Metallurgy and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaMore by Xian Huang
- Zhijun GuoZhijun GuoThe State Key Laboratory of Refractories and Metallurgy and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaMore by Zhijun Guo
- Qingwei LiQingwei LiWuhan National Laboratory for Optoelectronics (WNLO), School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaDepartment of Physics and Department of Materials Science and Engineering, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong 999077, ChinaMore by Qingwei Li
- Xuming ZhangXuming ZhangThe State Key Laboratory of Refractories and Metallurgy and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaMore by Xuming Zhang
- Paul K. ChuPaul K. ChuDepartment of Physics and Department of Materials Science and Engineering, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong 999077, ChinaMore by Paul K. Chu
- Kaifu Huo*Kaifu Huo*E-mail : [email protected]The State Key Laboratory of Refractories and Metallurgy and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaWuhan National Laboratory for Optoelectronics (WNLO), School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaMore by Kaifu Huo
Abstract
![Abstract Image](/cms/10.1021/acsami.8b17376/asset/images/medium/am-2018-17376d_0001.gif)
Lithium–sulfur (Li–S) batteries are promising next-generation energy storage devices because of their high energy density of 2600 Wh kg–1. Efficient immobilization and fast conversion of soluble lithium polysulfide intermediates (LiPSs) are crucial to the electrochemical performance of Li–S batteries. Herein, we report a novel strategy to simultaneously achieve large capacity, high rate capability, and long cycle life by utilizing mesoporous niobium nitride microspheres/N-doped graphene nanosheets (NbN@NG) hybrids as multifunctional host materials for sulfur cathodes. The mesoporous NbN microspheres chemically immobilize LiPSs via Nb–S chemical bonding and catalytically promote conversion of LiPSs into insoluble Li2S resulting in enhanced redox reaction kinetics. Moreover, the highly conductive NbN and N-doped graphene nanosheets provide rapid electron transport and consequently, the S/NbN@NG cathode demonstrates a large capacity of 948 mAh g–1 at 1C (1C = 1650 mA g–1), high rate capability of 739 mAh g–1 at 5C, and excellent cycle stability with a capacity decay of 0.09% per cycle for over 400 cycles. The results described here provide insights into the design of multifunctional host materials for high-performance Li–S batteries.
Cited By
This article is cited by 64 publications.
- Yanggu Liu, Shoujie Guan, Xuesen Du, Yanrong Chen, Yang Yang, Kunlu Chen, Ziwen Zheng, Xing Wang, Xiaoqiang Shen, Chenlong Hu, Xinbao Li. S-Vacancy Defect and Transition-Metal Atom Doping to Trigger Hydrogen Evolution of Two-Dimensional MoS2. Energy & Fuels 2023, 37
(7)
, 5370-5377. https://doi.org/10.1021/acs.energyfuels.2c03942
- Hongpeng Jia, Dashuai Wang, Yanjuan Li, Lihuai Liu, Hongfei Gu, Shun Yang, Qiang Fu, Xiao Yan, Yingjin Wei. Mesoporous Niobium Nitride Nanowires Encapsulated in Carbon for High-Performance Lithium–Sulfur Batteries. ACS Applied Nano Materials 2021, 4
(3)
, 2606-2613. https://doi.org/10.1021/acsanm.0c03256
- Hang Zhao, Bingbing Tian, Chenliang Su, Ying Li. Single-Atom Iron and Doped Sulfur Improve the Catalysis of Polysulfide Conversion for Obtaining High-Performance Lithium–Sulfur Batteries. ACS Applied Materials & Interfaces 2021, 13
(6)
, 7171-7177. https://doi.org/10.1021/acsami.0c20446
- Ruiqing Liu, Wenhui Liu, Yali Bu, Weiwei Yang, Cheng Wang, Cameron Priest, Zhiwei Liu, Yizhou Wang, Jianyu Chen, Yunhui Wang, Jie Cheng, Xiujing Lin, Xiaomiao Feng, Gang Wu, Yanwen Ma, Wei Huang. Conductive Porous Laminated Vanadium Nitride as Carbon-Free Hosts for High-Loading Sulfur Cathodes in Lithium–Sulfur Batteries. ACS Nano 2020, 14
(12)
, 17308-17320. https://doi.org/10.1021/acsnano.0c07415
- Dawei Yang, Chaoqi Zhang, Jordi Jacas Biendicho, Xu Han, Zhifu Liang, Ruifeng Du, Mengyao Li, Junshan Li, Jordi Arbiol, Jordi Llorca, Yingtang Zhou, Joan Ramon Morante, Andreu Cabot. ZnSe/N-Doped Carbon Nanoreactor with Multiple Adsorption Sites for Stable Lithium–Sulfur Batteries. ACS Nano 2020, 14
(11)
, 15492-15504. https://doi.org/10.1021/acsnano.0c06112
- Maoxu Wang, Lishuang Fan, Xun Sun, Bin Guan, Bo Jiang, Xian Wu, Da Tian, Kening Sun, Yue Qiu, Xiaoju Yin, Yu Zhang, Naiqing Zhang. Nitrogen-Doped CoSe2 as a Bifunctional Catalyst for High Areal Capacity and Lean Electrolyte of Li–S Battery. ACS Energy Letters 2020, 5
(9)
, 3041-3050. https://doi.org/10.1021/acsenergylett.0c01564
- Dan Luo, Zhen Zhang, Gaoran Li, Shaobo Cheng, Shuang Li, Jingde Li, Rui Gao, Matthew Li, Serubbabel Sy, Ya-Ping Deng, Yi Jiang, Yanfei Zhu, Haozhen Dou, Yongfeng Hu, Aiping Yu, Zhongwei Chen. Revealing the Rapid Electrocatalytic Behavior of Ultrafine Amorphous Defective Nb2O5–x Nanocluster toward Superior Li–S Performance. ACS Nano 2020, 14
(4)
, 4849-4860. https://doi.org/10.1021/acsnano.0c00799
- Yang Yang, Yutong Wang, Hai-Long He, Wenjun Yan, Li Fang, Yue-Biao Zhang, Yong Qin, Run Long, Xian-Ming Zhang, Xiujun Fan. Covalently Connected Nb4N5–xOx–MoS2 Heterocatalysts with Desired Electron Density to Boost Hydrogen Evolution. ACS Nano 2020, 14
(4)
, 4925-4937. https://doi.org/10.1021/acsnano.0c01072
- Liying Bao, Jinyu Yao, Shuangyi Zhao, Yun Lu, Yuefeng Su, Lai Chen, Chenying Zhao, Feng Wu. Densely Packed 3D Corrugated Papery Electrodes as Polysulfide Reservoirs for Lithium–Sulfur Battery with Ultrahigh Volumetric Capacity. ACS Sustainable Chemistry & Engineering 2020, 8
(14)
, 5648-5661. https://doi.org/10.1021/acssuschemeng.0c00243
- Seoa Kim, Won-Gwang Lim, Ara Cho, Jooyoung Jeong, Changshin Jo, DongGyu Kang, Seung Min Han, Jeong Woo Han, Jinwoo Lee. Simultaneous Suppression of Shuttle Effect and Lithium Dendrite Growth by Lightweight Bifunctional Separator for Li–S Batteries. ACS Applied Energy Materials 2020, 3
(3)
, 2643-2652. https://doi.org/10.1021/acsaem.9b02350
- Zhen-Dong Huang, Yanwu Fang, Mingtong Yang, Jike Yang, Yizhou Wang, Zhen Wu, Qingchuan Du, Titus Masese, Ruiqing Liu, Xusheng Yang, Chenhui Qian, Shaowei Jin, Yanwen Ma. Sulfur in Mesoporous Tungsten Nitride Foam Blocks: A Rational Lithium Polysulfide Confinement Experimental Design Strategy Augmented by Theoretical Predictions. ACS Applied Materials & Interfaces 2019, 11
(22)
, 20013-20021. https://doi.org/10.1021/acsami.9b04246
- Liyuan Zheng, Zhijun Zhu, Yutong Kuai, Qiaotong Huang, Mingkun Zhang, Yi Wang, Aiju Li. Modification of separators with neodymium oxide/graphene composite to enhance lithium-sulfur battery performance. Journal of Rare Earths 2024, 42
(9)
, 1730-1739. https://doi.org/10.1016/j.jre.2023.09.006
- Miao Sun, Jin Luo, Shuang Wang, Yinhua Wang, Haijun Zhang, Wen Lei. Tube‐in‐Tube Structure Design and
In
‐
situ
Growth of Fe
3
C for Efficient Reaction Kinetics in Lithium‐Sulfur Batteries. Batteries & Supercaps 2024, 36 https://doi.org/10.1002/batt.202400224
- Haining Fan, Xuan-Wen Gao, Hailong Xu, Yichun Ding, Shi-Xue Dou, Wen-Bin Luo. Catalytic effect in lithium metal batteries: From heterogeneous catalyst to homogenous catalyst. Journal of Energy Chemistry 2024, 90 , 305-326. https://doi.org/10.1016/j.jechem.2023.11.025
- Chuanxin Zong, Jiahao Gu, Peng Wang, Chenyang Shi, Shiyu Shao, Mengran Wang, Bo Hong, Jianhong Yang. Ammonium silicofluoride as bifunctional electrolyte additive to regulate the electrode interface in lithium-sulfur battery. Ionics 2024, 30
(3)
, 1383-1389. https://doi.org/10.1007/s11581-023-05331-1
- Guo Liu, Qi Zeng, Shuhao Tian, Xiao Sun, Di Wang, Qingfeng Wu, Wei Wei, Tianyu Wu, Yuhao Zhang, Yanbin Sheng, Kun Tao, Erqing Xie, Zhenxing Zhang. Boosting Polysulfide Redox Kinetics by Temperature‐Induced Metal‐Insulator Transition Effect of Tungsten‐Doped Vanadium Dioxide for High‐Temperature Lithium‐Sulfur Batteries. Small 2024, 20
(13)
https://doi.org/10.1002/smll.202307040
- Fei Ma, Zhuo Chen, Katam Srinivas, Ziheng Zhang, Yu Wu, Dawei Liu, Hesheng Yu, Yue Wang, Xinsheng Li, Ming-qiang Zhu, Qi Wu, Yuanfu Chen. NbN quantum dots anchored hollow carbon nanorods as efficient polysulfide immobilizer and lithium stabilizer for Li-S full batteries. Journal of Energy Chemistry 2024, 88 , 260-271. https://doi.org/10.1016/j.jechem.2023.09.027
- Na Ye, Wenchao Sheng, Riguang Zhang, Binhang Yan, Zhao Jiang, Tao Fang. Interfacial Electron Engineering of PdSn‐NbN/C for Highly Efficient Cleavage of the C–C Bonds in Alkaline Ethanol Electrooxidation. Small 2024, 20
(3)
https://doi.org/10.1002/smll.202304990
- Rui-Qing Liu, Feng Jin, Min Gu, Dong-Wen Zhang, Lu-Lu He, Wen-Xiu Liu, Wen-Feng Zhu, Kun Xie, Jing-Yi Wu, Yi-Ran Liu, Wei-Wei Yang, Xiu-Jing Lin, Li Shi, Xiao-Miao Feng, Zhen Hou, Ji-Gang Zhou, Yan-Wen Ma. Titanium nitride nanorod array/carbon cloth as flexible integrated host for highly stable lithium–sulfur batteries. Rare Metals 2023, 42
(12)
, 4115-4127. https://doi.org/10.1007/s12598-023-02367-0
- Yang Yang, Lijia Liu, Shuai Chen, Wenjun Yan, Haiqing Zhou, Xian‐Ming Zhang, Xiujun Fan. Tuning Binding Strength of Multiple Intermediates towards Efficient pH‐universal Electrocatalytic Hydrogen Evolution by Mo
8
O
26
‐NbN
x
O
y
Heterocatalysts. Angewandte Chemie 2023, 135
(46)
https://doi.org/10.1002/ange.202306896
- Yang Yang, Lijia Liu, Shuai Chen, Wenjun Yan, Haiqing Zhou, Xian‐Ming Zhang, Xiujun Fan. Tuning Binding Strength of Multiple Intermediates towards Efficient pH‐universal Electrocatalytic Hydrogen Evolution by Mo
8
O
26
‐NbN
x
O
y
Heterocatalysts. Angewandte Chemie International Edition 2023, 62
(46)
https://doi.org/10.1002/anie.202306896
- Shanying Wang, Ziwei Wang, Fangzheng Chen, Bo Peng, Jie Xu, Junzhe Li, Yaohui Lv, Qi Kang, Ailin Xia, Lianbo Ma. Electrocatalysts in lithium-sulfur batteries. Nano Research 2023, 16
(4)
, 4438-4467. https://doi.org/10.1007/s12274-022-5215-4
- Nan Shen, Hongxu Sun, Boya Li, Baojuan Xi, Xuguang An, Jingfa Li, Shenglin Xiong. Dual‐Functional Hosts for Polysulfides Conversion and Lithium Plating/Stripping towards Lithium‐Sulfur Full Cells. Chemistry – A European Journal 2023, 29
(11)
https://doi.org/10.1002/chem.202203031
- Xuanhe Hu, Tian Huang, Gengyuan Zhang, Shangjun Lin, Ruwei Chen, Lai-Hon Chung, Jun He. Metal-organic framework-based catalysts for lithium-sulfur batteries. Coordination Chemistry Reviews 2023, 475 , 214879. https://doi.org/10.1016/j.ccr.2022.214879
- Longgang Li, Xianfei Chen, Yi Huang, Peicong Zhang, Dan Zhou, Guanru Zhang, Beibei Xiao. Double-active-site enables 2D B2S and B2S3 catalyst with suppressed shuttle effect and improved polysulfides redox kinetics in lithium-sulfur batteries: A first-principles study. Applied Surface Science 2022, 602 , 154295. https://doi.org/10.1016/j.apsusc.2022.154295
- Junjie Fu, Zewei Shen, Daoping Cai, Ban Fei, Chaoqi Zhang, Yaguang Wang, Qidi Chen, Hongbing Zhan. A hierarchical VN/Co
3
ZnC@NCNT composite as a multifunctional integrated host for lithium–sulfur batteries with enriched adsorption sites and accelerated conversion kinetics. Journal of Materials Chemistry A 2022, 10
(38)
, 20525-20534. https://doi.org/10.1039/D2TA06231C
- Lei Wang, Xiaofang Li, Yingxi Zhang, Weijian Mao, Yuanyuan Li, Paul K. Chu, Abdulkadir Kızılaslan, Zijian Zheng, Kaifu Huo. Subnanometer MoP clusters confined in mesoporous carbon (CMK-3) as superior electrocatalytic sulfur hosts for high-performance lithium-sulfur batteries. Chemical Engineering Journal 2022, 446 , 137050. https://doi.org/10.1016/j.cej.2022.137050
- Ning Wang. Graphene‐Based Materials for
Li
–
S
Batteries. 2022, 189-213. https://doi.org/10.1002/9783527822089.ch8
- Saisai Qiu, Xinqi Liang, Shuwen Niu, Qingguo Chen, Gongming Wang, Minghua Chen. Quantitative defect regulation of heterostructures for sulfur catalysis toward fast and long lifespan lithium-sulfur batteries. Nano Research 2022, 15
(9)
, 7925-7932. https://doi.org/10.1007/s12274-022-4453-9
- Ziwei Liang, Jiadong Shen, Xijun Xu, Fangkun Li, Jun Liu, Bin Yuan, Yan Yu, Min Zhu. Advances in the Development of Single‐Atom Catalysts for High‐Energy‐Density Lithium–Sulfur Batteries. Advanced Materials 2022, 34
(30)
https://doi.org/10.1002/adma.202200102
- Peng Wang, Yunhe Song, Zhenming Xu, Na Li, Jinfeng Sun, Bo Hong, Yanqing Lai. Hierarchical Mo
x
C@NC hollow microsphere with incorporated Mo vacancies as multifunctional confined reactors for high-loading Li–S batteries. Inorganic Chemistry Frontiers 2022, 9
(10)
, 2194-2203. https://doi.org/10.1039/D1QI01649K
- Shaowen Zhou, Chao‐Lung Chiang, Jianqing Zhao, Guanjian Cheng, Tariq Bashir, Wanjian Yin, Junyi Yao, Shiqi Yang, Wanying Li, Jiaqi Wang, Xinyuan Wang, Yan‐Gu Lin, Lijun Gao. Extra Storage Capacity Enabled by Structural Defects in Pseudocapacitive NbN Monocrystals for High‐Energy Hybrid Supercapacitors. Advanced Functional Materials 2022, 32
(22)
https://doi.org/10.1002/adfm.202112592
- Nianxiang Shi, Baojuan Xi, Jie Liu, Zhengchunyu Zhang, Ning Song, Weihua Chen, Jinkui Feng, Shenglin Xiong. Dual‐Functional NbN Ultrafine Nanocrystals Enabling Kinetically Boosted Lithium–Sulfur Batteries. Advanced Functional Materials 2022, 32
(17)
https://doi.org/10.1002/adfm.202111586
- Xinye Liu, Shanxing Wang, Huanhuan Duan, Yuanfu Deng, Guohua Chen. A thin and multifunctional CoS@g-C3N4/Ketjen black interlayer deposited on polypropylene separator for boosting the performance of lithium-sulfur batteries. Journal of Colloid and Interface Science 2022, 608 , 470-481. https://doi.org/10.1016/j.jcis.2021.09.122
- Wenjia Qu, Chuannan Geng, Jingyi Xia, Wuxing Hua, Guowei Ling, Chen Zhang, Quan-Hong Yang. Catalytic Conversion of Polysulfides in Li–S Batteries. 2022, 165-223. https://doi.org/10.1007/978-3-030-90899-7_5
- Xingyuan Zhang, Xiaoli Lv, Chunguang Wei, Jian-Gan Wang. Highly sulfiphilic zinc selenide/carbon regulators for high-capacity and long-lifespan Li-S batteries. Applied Surface Science 2021, 568 , 150952. https://doi.org/10.1016/j.apsusc.2021.150952
- Xi Wang, Sining Yun, Yongwei Zhang, Lishan Zhang, Jiaoe Dang, Menglong Sun, Zhuolei Liu, Yinhao Wang. Boosting catalytic activity of niobium/tantalum-nitrogen active-sites for triiodide reduction in photovoltaics. Journal of Colloid and Interface Science 2021, 603 , 651-665. https://doi.org/10.1016/j.jcis.2021.06.128
- Chao Zhou, Ming Li, Min Hong, Nantao Hu, Zhi Yang, Liying Zhang, Yafei Zhang. Laser-induced micro-explosion to construct hierarchical structure as efficient polysulfide mediators for high-performance lithium-sulfur batteries. Chemical Engineering Journal 2021, 421 , 129707. https://doi.org/10.1016/j.cej.2021.129707
- Munan Qiu, Xuewei Fu, Fan Yang, Shengli Qi, Zhanpeng Wu, Wei‐Hong Zhong. In‐Situ Synthesis of N, O, P‐Doped Hierarchical Porous Carbon from Poly‐bis(phenoxy)phosphazene for Polysulfide‐Trapping Interlayer in Lithium‐Sulfur Batteries. Chemistry – A European Journal 2021, 27
(38)
, 9876-9884. https://doi.org/10.1002/chem.202100693
- Xierong Zeng, Jianxin Tu, Shuangshuang Chen, Shaozhong Zeng, Qi Zhang, Jizhao Zou, Kezhi Li. Microwave-assisted synthesis of Cr3C2@C core shell structure anchored on hierarchical porous carbon foam for enhanced polysulfide adsorption in Li-S batteries. Nano Research 2021, 14
(7)
, 2345-2352. https://doi.org/10.1007/s12274-020-3233-7
- Jingyi Xia, Wuxing Hua, Li Wang, Yafei Sun, Chuannan Geng, Chen Zhang, Weichao Wang, Ying Wan, Quan‐Hong Yang. Boosting Catalytic Activity by Seeding Nanocatalysts onto Interlayers to Inhibit Polysulfide Shuttling in Li–S Batteries. Advanced Functional Materials 2021, 31
(26)
https://doi.org/10.1002/adfm.202101980
- Lu Wang, Guo‐Ran Li, Sheng Liu, Xue‐Ping Gao. Hollow Molybdate Microspheres as Catalytic Hosts for Enhancing the Electrochemical Performance of Sulfur Cathode under High Sulfur Loading and Lean Electrolyte. Advanced Functional Materials 2021, 31
(18)
https://doi.org/10.1002/adfm.202010693
- Yan-juan LI, Min WANG, Sa LIU, Jing-xia GAO, Shun YANG, Zi-hao LIU, Xiao-yong LAI, Xiao YAN. Preparation and properties of transition metal nitrides caged in N-doped hollow porous carbon sphere for oxygen reduction reaction. Transactions of Nonferrous Metals Society of China 2021, 31
(5)
, 1427-1438. https://doi.org/10.1016/S1003-6326(21)65587-5
- Qinqin Huang, Mingqi Chen, Zhe Su, Liying Tian, Yayun Zhang, Donghui Long. Rational cooperativity of nanospace confinement and rapid catalysis via hollow carbon nanospheres@Nb-based inorganics for high-rate Li-S batteries. Chemical Engineering Journal 2021, 411 , 128504. https://doi.org/10.1016/j.cej.2021.128504
- Lei Zhou, Dmitri L. Danilov, Rüdiger‐A. Eichel, Peter H. L. Notten. Host Materials Anchoring Polysulfides in Li–S Batteries Reviewed. Advanced Energy Materials 2021, 11
(15)
https://doi.org/10.1002/aenm.202001304
- Xinzhe Yang, Tingting Qin, Xiaoyu Zhang, Xiaofei Liu, Zizhun Wang, Wei Zhang, Weitao Zheng. Self-crystallized Interlayer Integrating Polysulfide-adsorbed TiO2/TiO and Highly-electron-conductive TiO for High-stability Lithium-sulfur Batteries. Chemical Research in Chinese Universities 2021, 37
(2)
, 259-264. https://doi.org/10.1007/s40242-020-0310-0
- Jingfa Li, Zhihao Niu, Cong Guo, Min Li, Weizhai Bao. Catalyzing the polysulfide conversion for promoting lithium sulfur battery performances: A review. Journal of Energy Chemistry 2021, 54 , 434-451. https://doi.org/10.1016/j.jechem.2020.06.009
- Shuangshuang Tan, Yuhang Dai, Yalong Jiang, Qiulong Wei, Guobin Zhang, Fangyu Xiong, Xingqi Zhu, Zhi‐Yi Hu, Liang Zhou, Yongcheng Jin, Kiyoshi Kanamura, Qinyou An, Liqiang Mai. Revealing the Origin of Highly Efficient Polysulfide Anchoring and Transformation on Anion‐Substituted Vanadium Nitride Host. Advanced Functional Materials 2021, 31
(7)
https://doi.org/10.1002/adfm.202008034
- Hao Wang, Jianmin Li, Ke Li, Yanping Lin, Jianmei Chen, Lijun Gao, Valeria Nicolosi, Xu Xiao, Jong-Min Lee. Transition metal nitrides for electrochemical energy applications. Chemical Society Reviews 2021, 50
(2)
, 1354-1390. https://doi.org/10.1039/D0CS00415D
- Binren Fang, Xiaolu Tian, Te Wang, Tao Wang, Long Qu, Mingtao Li. Restraining Polysulfide with High‐Entropy Metal Nitride towards Long Cycle Life and High Capacity Li−S Batteries. ChemElectroChem 2020, 7
(23)
, 4737-4744. https://doi.org/10.1002/celc.202001215
- Nanping Deng, Yang Feng, Gang Wang, Xiaoxiao Wang, Liyuan Wang, Quanxiang Li, Leitao Zhang, Weimin Kang, Bowen Cheng, Yong Liu. Rational structure designs of 2D materials and their applications toward advanced lithium-sulfur battery and lithium-selenium battery. Chemical Engineering Journal 2020, 401 , 125976. https://doi.org/10.1016/j.cej.2020.125976
- Ting Yang, Caixia Zhang, Hui Li, Zhanzhong Wang, Jingyu Zhang, Xiaojing Wang, Zhanli Chai. Pt/N-rGO/Nb4N5 Electrocatalyst with Multilayered Structure and Ternary Synergy for Promoting Alcohol Oxidation. Journal of Alloys and Compounds 2020, 845 , 156117. https://doi.org/10.1016/j.jallcom.2020.156117
- Yue Lian, Ning Yang, Dawei Wang, Yujing Zheng, Chaolei Ban, Jing Zhao, Huaihao Zhang. Optimization Design and Application of Niobium‐Based Materials in Electrochemical Energy Storage. Advanced Energy and Sustainability Research 2020, 1
(1)
https://doi.org/10.1002/aesr.202000038
- Lu Wang, Zhen-Yu Wang, Jun-Feng Wu, Guo-Ran Li, Sheng Liu, Xue-Ping Gao. To effectively drive the conversion of sulfur with electroactive niobium tungsten oxide microspheres for lithium−sulfur battery. Nano Energy 2020, 77 , 105173. https://doi.org/10.1016/j.nanoen.2020.105173
- Sanket Bhoyate, Junyoung Kim, Eunho Lee, Bumsu Park, Eunji Lee, Juhong Park, Sang Ho Oh, Jeongyong Kim, Wonbong Choi. Mixed phase 2D Mo
0.5
W
0.5
S
2
alloy as a multi-functional electrocatalyst for a high-performance cathode in Li–S batteries. Journal of Materials Chemistry A 2020, 8
(25)
, 12436-12445. https://doi.org/10.1039/D0TA04354K
- Huifa Shi, Zhenhua Sun, Wei Lv, Shujie Xiao, Huicong Yang, Ying Shi, Ke Chen, Shaogang Wang, Bingsen Zhang, Quan-Hong Yang, Feng Li. Efficient polysulfide blocker from conductive niobium nitride@graphene for Li-S batteries. Journal of Energy Chemistry 2020, 45 , 135-141. https://doi.org/10.1016/j.jechem.2019.10.018
- Weini Ge, Lu Wang, Chuanchuan Li, Chunsheng Wang, Debao Wang, Yitai Qian, Liqiang Xu. Conductive cobalt doped niobium nitride porous spheres as an efficient polysulfide convertor for advanced lithium-sulfur batteries. Journal of Materials Chemistry A 2020, 8
(13)
, 6276-6282. https://doi.org/10.1039/D0TA00800A
- Yingze Song, Wenlong Cai, Long Kong, Jingsheng Cai, Qiang Zhang, Jingyu Sun. Rationalizing Electrocatalysis of Li–S Chemistry by Mediator Design: Progress and Prospects. Advanced Energy Materials 2020, 10
(11)
https://doi.org/10.1002/aenm.201901075
- Yang Zheng, Xingxing Li, Chaoran Pi, Hao Song, Biao Gao, Paul K Chu, Kaifu Huo. Recent advances of two-dimensional transition metal nitrides for energy storage and conversion applications. FlatChem 2020, 19 , 100149. https://doi.org/10.1016/j.flatc.2019.100149
- Shuang Fan, Shaozhuan Huang, Mei Er Pam, Song Chen, Qingyun Wu, Junping Hu, Ye Wang, Lay Kee Ang, Congcong Yan, Yumeng Shi, Hui Ying Yang. Design Multifunctional Catalytic Interface: Toward Regulation of Polysulfide and Li
2
S Redox Conversion in Li–S Batteries. Small 2019, 15
(51)
https://doi.org/10.1002/smll.201906132
- Xiudong Chen, Yanjun Xu, Fei‐Hu Du, Yong Wang. Covalent Organic Framework Derived Boron/Oxygen Codoped Porous Carbon on CNTs as an Efficient Sulfur Host for Lithium–Sulfur Batteries. Small Methods 2019, 3
(11)
https://doi.org/10.1002/smtd.201900338
- Liang Chen, Weiwei Yang, Jianguo Liu, Yong Zhou. Decorating CoSe2 hollow nanospheres on reduced graphene oxide as advanced sulfur host material for performance enhanced lithium-sulfur batteries. Nano Research 2019, 12
(11)
, 2743-2748. https://doi.org/10.1007/s12274-019-2508-3
- Yingze Song, Zhongti Sun, Jingsheng Cai, Nan Wei, Menglei Wang, Yuanlong Shao, Zhongfan Liu, Jingyu Sun. Accelerated Li–S chemistry at a cooperative interface built
in situ. Journal of Materials Chemistry A 2019, 7
(36)
, 20750-20759. https://doi.org/10.1039/C9TA07342F
- Huifa Shi, Zhenhua Sun, Wei Lv, Shaogang Wang, Ying Shi, Yunbo Zhang, Shujie Xiao, Huicong Yang, Quan-Hong Yang, Feng Li. Necklace-like MoC sulfiphilic sites embedded in interconnected carbon networks for Li–S batteries with high sulfur loading. Journal of Materials Chemistry A 2019, 7
(18)
, 11298-11304. https://doi.org/10.1039/C9TA00741E
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.